Chemical symbol
Chemical symbols are the abbreviations used in chemistry, mainly for chemical elements, but also for functional groups, chemical compounds, and other entities. Element symbols for chemical elements, also known as atomic symbols, normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised.
History
Earlier symbols for chemical elements stem from classical Latin and Greek words. For some elements, this is because the material was known in ancient times, while for others, the name is a more recent invention. For example, Pb is the symbol for lead ; Hg is the symbol for mercury ; and He is the symbol for helium because helium was not known in ancient Roman times. Some symbols come from other sources, like W for tungsten which was not known in Roman times.A three-letter temporary symbol may be assigned to a newly synthesized element. For example, "Uno" was the temporary symbol for hassium which had the temporary name of unniloctium, based on the digits of its atomic number. There are also some historical symbols that are no longer officially used.
Extension of the symbol
In addition to the letters for the element itself, additional details may be added to the symbol as superscripts or subscripts a particular isotope, ionization, or oxidation state, or other atomic detail. A few isotopes have their own specific symbols rather than just an isotopic detail added to their element symbol.Attached subscripts or superscripts specifying a nuclide or molecule have the following meanings and positions:
- The nucleon number is shown in the left superscript position. This number defines the specific isotope. Various letters, such as "m" and "f" may also be used here to indicate a nuclear isomer. Alternately, the number here can represent a specific spin state. These details can be omitted if not relevant in a certain context.
- The proton number may be indicated in the left subscript position. The atomic number is redundant to the chemical element, but is sometimes used to emphasize the change of numbers of nucleons in a nuclear reaction.
- If necessary, a state of ionization or an excited state may be indicated in the right superscript position.
- The number of atoms of an element in a molecule or chemical compound is shown in the right subscript position. If this number is one, it is normally omitted - the number one is implicitly understood if unspecified.
- A radical is indicated by a dot on the right side. This is often omitted unless relevant to a certain context because it is already deducible from the charge and atomic number, as generally true for nonbonded valence electrons in skeletal structures.
A list of current, dated, as well as proposed and historical signs and symbols is included here with its signification. Also given is each element's atomic number, atomic weight, or the atomic mass of the most stable isotope, group and period numbers on the periodic table, and etymology of the symbol.
Symbols and names not currently used
The following is a list of symbols and names formerly used or suggested for elements, including symbols for placeholder names and names given by discredited claimants for discovery.| Symbol | Name | Atomic number | Notes | Why not used | Refs |
| A | Argon | 18 | A used for Argon until 1957. Current symbol is Ar. | ||
| Ab | Alabamine | 85 | Discredited claim to discovery of astatine. | ||
| Ad | Aldebaranium | 70 | Former name for ytterbium. | ||
| Ah | Anglohelvetium | 85 | Discredited claim to discovery of astatine. | ||
| Ak | Alkalinium | 87 | Discredited claim to discovery of francium. | ||
| Am | Alabamine | 85 | Discredited claim to discovery of astatine. The symbol Am is now used for americium. | ||
| An | Athenium | 99 | Proposed name for einsteinium. | ||
| Ao | Ausonium | 93 | Discredited claim to discovery of neptunium. | ||
| At | Austriacum | 84 | Discredited claim to discovery of polonium. The symbol At is now used for astatine. | ||
| Az | Azote | 7 | Former name for nitrogen. | ||
| Bo | Bohemium | 93 | Discredited claim to discovery of neptunium. | ||
| Bo | Boron | 5 | Current symbol is B. | ||
| Bv | Brevium | 91 | Former name for protactinium-234. | ||
| Bz | Berzelium | 90 | Baskerville wrongly believed berzelium was a new element. Was actually thorium. | ||
| Cb | Columbium | 41 | Former name for niobium. | ||
| Ch | Chromium | 24 | Current symbol is Cr. | ||
| Cl | Columbium | 41 | Former name for niobium. The symbol Cl is now used for chlorine. | ||
| Cm | Catium | 87 | Proposed name for francium. The symbol Cm is now used for curium. | ||
| Cn | Carolinium | 90 | Baskerville wrongly believed carolinium to be a new element. Was actually thorium. The symbol Cn is now used for copernicium. | ||
| Cp | Cassiopeium | 71 | Former name for lutetium. | ||
| Cp | Copernicium | 112 | Current symbol is Cn. | ||
| Ct | Celtium | 72 | Discredited claim to discovery of hafnium. | ||
| Ct | Centurium | 100 | Proposed name for fermium. | ||
| Cy | Cyclonium | 61 | Proposed name for promethium. | ||
| D | Didymium | 59/60 | Mixture of the elements praseodymium and neodymium. Mosander wrongly believed didymium to be an element. | ||
| Da | Davyum | 43 | Discredited claim to discovery of technetium. | ||
| Db | Dubhium | 69 | Eder wrongly believed dubhium to be a new element. Was actually thulium. The symbol Db is now used for dubnium. | ||
| Db | Dubnium | 104 | Proposed name for rutherfordium. The symbol and name were instead used for element 105. | ||
| Dc | Decipium | 62 | Delafontaine wrongly believed decipium to be a new element. Was actually samarium. | ||
| Dc | Dvicaesium | 87 | Name given by Mendeleev to an as of then undiscovered element. When discovered, francium closely matched the prediction. | ||
| De | Denebium | 69 | Eder wrongly believed denebium to be a new element. Was actually thulium. | ||
| Di | Didymium | 59/60 | Mixture of the elements praseodymium and neodymium. Mosander wrongly believed didymium to be an element. | ||
| Do | Dor | 85 | Discredited claim to discovery of astatine made by Horia Hulubei and Yvette Cauchois. | ||
| Dn | Dubnadium | 118 | Proposed name for oganesson. | ||
| Dp | Decipium | 62 | Delafontaine wrongly believed decipium to be a new element. Was actually samarium. | ||
| Ds | Dysprosium | 66 | Current symbol is Dy. The symbol Ds is now used for darmstadtium. | ||
| Dt | Dvitellurium | 84 | Name given by Mendeleev to an as of then undiscovered element. When discovered, polonium closely matched the prediction. | ||
| E | Einsteinium | 99 | Current symbol is Es. | ||
| E | Erbium | 68 | Current symbol is Er. | ||
| Ea | Ekaaluminium | 31 | Name given by Mendeleev to an as of then undiscovered element. When discovered, gallium closely matched the prediction. | ||
| Eb | Ekaboron | 21 | Name given by Mendeleev to an as of then undiscovered element. When discovered, scandium closely matched the prediction. | ||
| Eb | Erebodium | 42 | Alexander Pringle wrongly believed erebodium to be a new element. Was likely molybdenum. | ||
| El | Ekaaluminium | 31 | Name given by Mendeleev to an as of then undiscovered element. When discovered, gallium closely matched the prediction. | ||
| Em | Ekamanganese | 43 | Name given by Mendeleev to an as of then undiscovered element. When discovered, technetium closely matched the prediction. | ||
| Em | Emanation | 86 | Also called "radium emanation", the name was originally given by Friedrich Ernst Dorn in 1900. In 1923, this element officially became radon. | ||
| Em | Emanium | 89 | Alternate name formerly proposed for actinium. | ||
| Es | Ekasilicon | 32 | Name given by Mendeleev to a then undiscovered element. When discovered, germanium closely matched the prediction. The symbol Es is now used for einsteinium. | ||
| Hs | Hesperium | 94 | Discredited claim to discovery of plutonium. The symbol Hs is now used for hassium. | ||
| Et | Ekatantalum | 91 | Name given by Mendeleev to an as of then undiscovered element. When discovered, protactinium closely matched the prediction. | ||
| Ex | Euxenium | 72 | Discredited claim to discovery of hafnium. | ||
| Fa | Francium | 87 | Current symbol is Fr. | ||
| Fl | Florentium | 61 | Discredited claim to discovery of promethium. The symbol Fl is now used for flerovium. | ||
| Fl | Fluorine | 9 | Current symbol is F. The symbol Fl is now used for flerovium. | ||
| Fr | Florentium | 61 | Discredited claim to discovery of promethium. The symbol Fr is now used for francium. | ||
| G | Glucinium | 4 | Former name for beryllium. | ||
| Gh | Ghiorsium | 118 | Discredited claim to discovery of oganesson. | ||
| Gl | Glucinium | 4 | Former name for beryllium. | ||
| Ha | Hahnium | 105 | Proposed name for dubnium. | ||
| Hn | Hahnium | 108 | Proposed name for hassium. | ||
| Hv | Helvetium | 85 | Discredited claim to discovery of astatine. | ||
| Hy | Mercury | 80 | Hy from the Greek hydrargyrum for "liquid silver". Current symbol is Hg. | ||
| I | Iridium | 77 | Current symbol is Ir. The symbol I is now used for iodine. | ||
| Ic | Incognitium | 65 | Demarçay wrongly believed incognitium to be a new element. Was actually terbium mixed with gadolinium. | ||
| Il | Illinium | 61 | Discredited claim to discovery of promethium. | ||
| Il | Ilmenium | 41/73 | Mixture of the elements niobium and tantalum. R. Hermann wrongly believed ilmenium to be an element. | ||
| Io | Ionium | 65 | Demarçay wrongly believed ionium to be a new element. Was actually terbium. | ||
| J | Jodium | 53 | Former name for iodine. | ||
| Jg | Jargonium | 72 | Discredited claim to discovery of hafnium. | ||
| Jl | Joliotium | 105 | Proposed name for dubnium. | ||
| Jp | Japonium | 113 | Proposed name for nihonium. | ||
| Ka | Potassium | 19 | Current symbol is K. | ||
| Ku | Kurchatovium | 104 | Proposed name for rutherfordium. | ||
| L | Lithium | 3 | Current symbol is Li. | ||
| Lw | Lawrencium | 103 | Current symbol is Lr. | ||
| M | Muriaticum | 17 | Former name for chlorine. | ||
| Ma | Manganese | 25 | Current symbol is Mn. | ||
| Ma | Masurium | 43 | Disputed claim to discovery of technetium. | ||
| Md | Mendelevium | 97 | Proposed name for berkelium. The symbol and name were later used for element 101. | ||
| Ml | Moldavium | 87 | Discredited claim to discovery of francium made by Horia Hulubei and Yvette Cauchois. | ||
| Ms | Magnesium | 12 | Current symbol is Mg. | ||
| Ms | Masrium | 88 | Discredited claim to discovery of radium. | ||
| Ms | Masurium | 43 | Disputed claim to discovery of technetium. | ||
| Ms | Mosandrium | 65 | Smith wrongly believed mosandrium to be a new element. Was actually terbium. | ||
| Mv | Mendelevium | 101 | Current symbol is Md. | ||
| Ng | Norwegium | 72 | Discredited claim to discovery of hafnium. | ||
| No | Norium | 72 | Discredited claim to discovery of hafnium. The symbol No is now used for nobelium. | ||
| Np | Neptunium | 91 | Discredited claim to discovery of protactinium. The symbol and name were later used for element 93. | ||
| Np | Nipponium | 43 | Discredited claim to discovery of technetium. The symbol Np is now used for neptunium. | ||
| Ns | Nielsbohrium | 105 | Proposed name for dubnium. | ||
| Ns | Nielsbohrium | 107 | Proposed name for bohrium. | ||
| Nt | Niton | 86 | Former name for radon. | ||
| Ny | Neoytterbium | 70 | Former name for ytterbium. | ||
| P | Lead | 82 | Current symbol is Pb. The symbol P is now used for phosphorus. | ||
| Pa | Palladium | 46 | Current symbol is Pd. The symbol Pa is now used for protactinium. | ||
| Pe | Pelopium | 41 | Former name for niobium. | ||
| Ph | Phosphorus | 15 | Current symbol is P. | ||
| Pl | Palladium | 46 | Current symbol is Pd. | ||
| Pm | Polymnestum | 33 | Alexander Pringle wrongly believed polymnestum to be a new element. Was likely arsenic. The symbol Pm is now used for promethium. | ||
| Po | Potassium | 19 | Current symbol is K. The symbol Po is now used for polonium. | ||
| Pp | Philippium | 67 | Delafontaine discovered a new element and named it philippium. Per Teodor Cleve isolated it and renamed it holmium. | ||
| R | Rhodium | 45 | Current symbol is Rh. | ||
| Rd | Radium | 88 | Current symbol is Ra. | ||
| Rf | Rutherfordium | 106 | Proposed name for seaborgium. The symbol and name were instead used for element 104. | ||
| Ro | Rhodium | 45 | Current symbol is Rh. | ||
| Sa | Samarium | 62 | Current symbol is Sm. | ||
| So | Sodium | 11 | Current symbol is Na. | ||
| Sq | Sequanium | 93 | Discredited claim to discovery of neptunium made by Horia Hulubei and Yvette Cauchois. | ||
| St | Antimony | 51 | Current symbol is Sb. | ||
| St | Tin | 50 | Current symbol is Sn. | ||
| Tm | Trimanganese | 75 | Name given by Mendeleev to an as of then undiscovered element. When discovered, rhenium closely matched the prediction. The symbol Tm is now used for thulium. | ||
| Tn | Tungsten | 74 | Current symbol is W. | ||
| Tr | Terbium | 65 | Current symbol is Tb. | ||
| Tu | Thulium | 69 | Current symbol is Tm. | ||
| Tu | Tungsten | 74 | Current symbol is W. | ||
| Ur | Uralium | 75 | Discredited claim to discovery of rhenium. | ||
| Ur | Uranium | 92 | Current symbol is U. | ||
| Vc | Victorium | 64 | Crookes wrongly believed victorium to be a new element. Was actually gadolinium. | ||
| Vi | Victorium | 64 | Crookes wrongly believed victorium to be a new element. Was actually gadolinium. | ||
| Vi | Virginium | 87 | Discredited claim to discovery of francium. | ||
| Vm | Virginium | 87 | Discredited claim to discovery of francium. | ||
| Va | Vanadium | 23 | Current symbol is V. | ||
| Wo | Wolfram | 74 | Former name for tungsten. | ||
| X | Xenon | 54 | Current symbol is Xe. The symbol X is now used for any halogen. | ||
| Yt | Yttrium | 39 | Current symbol is Y. |
Systematic chemical symbols
These symbols are based on systematic element names, which are now replaced by trivial element names and symbols. Data is given in order of: atomic number, systematic symbol, systematic name; trivial symbol, trivial name.- 101: Unu, unnilunium; Md, mendelevium.
- 102: Unb, unnilbium; No, nobelium.
- 103: Unt, unniltrium; Lr, lawrencium.
- 104: Unq, unnilquadium; Rf, rutherfordium.
- 105: Unp, unnilpentium; Db, dubnium.
- 106: Unh, unnilhexium; Sg, seaborgium.
- 107: Uns, unnilseptium; Bh, bohrium.
- 108: Uno, unniloctium; Hs, hassium.
- 109: Une, unnilennium; Mt, meitnerium.
- 110: Uun, ununnilium; Ds, darmstadtium.
- 111: Uuu, unununium; Rg, roentgenium.
- 112: Uub, ununbium; Cn, copernicium.
- 113: Uut, ununtrium; Nh, nihonium.
- 114: Uuq, ununquadium; Fl, flerovium.
- 115: Uup, ununpentium; Mc, moscovium.
- 116: Uuh, ununhexium; Lv, livermorium.
- 117: Uus, ununseptium; Ts, tennessine.
- 118: Uuo, ununoctium; Og, oganesson.
Alchemical symbols
The following ideographic symbols were used in alchemy to denote elements known since ancient times. Not included in this list are spurious elements, such as the classical elements fire and water or phlogiston, and substances now known to be compounds. Many more symbols were in at least sporadic use: one early 17th-century alchemical manuscript lists 22 symbols for mercury alone.Planetary names and symbols for the metals – the seven planets and seven metals known since Classical times in Europe and the Mideast – was ubiquitous in alchemy. The association of what are anachronistically known as planetary metals started breaking down with the discovery of antimony, bismuth and zinc in the 16th century. Alchemists would typically call the metals by their planetary names, e.g. "Saturn" for lead and "Mars" for iron; compounds of tin, iron and silver continued to be called "jovial", "martial" and "lunar"; or "of Jupiter", "of Mars" and "of the moon", through the 17th century. The tradition remains today with the name of the element mercury, where chemists decided the planetary name was preferable to common names like "quicksilver", and in a few archaic terms such as lunar caustic and saturnism.
Daltonian symbols
The following symbols were employed by John Dalton in the early 1800s as the periodic table of elements was being formulated. Not included in this list are symbols for compounds, such as certain rare-earth mineral blends. Modern alphabetic notation was introduced in 1814 by Jöns Jakob Berzelius; its precursor can be seen in Dalton's circled letters for the metals, especially in his augmented table from 1810.A trace of Dalton's conventions also survives in ball-and-stick models of molecules, where balls for carbon are black and for oxygen red.
Symbols for named isotopes
The following is a list of isotopes which have been given unique symbols. This is not a list of current systematic symbols ; such a list can instead be found in Template:Navbox element isotopes. The symbols for isotopes of hydrogen, deuterium and tritium, are still in use today, as is thoron for radon-220. Heavy water and other deuterated solvents are commonly used in chemistry, and it is convenient to use a single character rather than a symbol with a superscript in these cases. The practice also continues with tritium compounds. When the name of the solvent is given, a lowercase d is sometimes used. For example, d-benzene or CD can be used instead of C.The symbols for isotopes of elements other than hydrogen and radon are no longer used in the scientific community. Many of these symbols were designated during the early years of radiochemistry, and several isotopes bear placeholder names using the early naming system devised by Ernest Rutherford.
| Symbol | Name | Atomic number | Origin of symbol |
| Ac | Actinium | 89 | From Greek aktinos. Name restricted at one time to Ac, an isotope of actinium. This named isotope later became the official name for element 89. |
| AcA | Actinium A | 84 | From actinium and A. Placeholder name given at one time to Po, an isotope of polonium identified in the decay chain of actinium. |
| AcB | Actinium B | 82 | From actinium and B. Placeholder name given at one time to Pb, an isotope of lead identified in the decay chain of actinium. |
| AcC | Actinium C | 83 | From actinium and C. Placeholder name given at one time to Bi, an isotope of bismuth identified in the decay chain of actinium. |
| AcC′ | Actinium C′ | 84 | From actinium and C′. Placeholder name given at one time to Po, an isotope of polonium identified in the decay chain of actinium. |
| AcC″ | Actinium C″ | 81 | From actinium and C″. Placeholder name given at one time to 207Tl, an isotope of thallium identified in the decay chain of actinium. |
| AcK | Actinium K | 87 | Name given at one time to 223Fr, an isotope of francium identified in the decay chain of actinium. |
| AcU | Actino-uranium | 92 | Name given at one time to 235U, an isotope of uranium. |
| AcX | Actinium X | 88 | Name given at one time to 223Ra, an isotope of radium identified in the decay chain of actinium. |
| An | Actinon | 86 | From actinium and emanation. Name given at one time to 219Rn, an isotope of radon identified in the decay chain of actinium. |
| D | Deuterium | 1 | From the Greek deuteros. Name given to 2H. |
| Io | Ionium | 90 | Name given to 230Th, an isotope of thorium identified in the decay chain of uranium. |
| MsTh1 | Mesothorium 1 | 88 | Name given at one time to 228Ra, an isotope of radium. |
| MsTh2 | Mesothorium 2 | 89 | Name given at one time to 228Ac, an isotope of actinium. |
| Pa | Protactinium | 91 | From the Greek protos and actinium. Name restricted at one time to 231Pa, an isotope of protactinium. This named isotope later became the official name for element 91. |
| Ra | Radium | 88 | From the Latin radius. Name restricted at one time to 226Ra, an isotope of radium. This named isotope later became the official name for element 88. |
| RaA | Radium A | 84 | From radium and A. Placeholder name given at one time to 218Po, an isotope of polonium identified in the decay chain of radium. |
| RaB | Radium B | 82 | From radium and B. Placeholder name given at one time to 214Pb, an isotope of lead identified in the decay chain of radium. |
| RaC | Radium C | 83 | From radium and C. Placeholder name given at one time to 214Bi, an isotope of bismuth identified in the decay chain of radium. |
| RaC′ | Radium C′ | 84 | From radium and C′. Placeholder name given at one time to 214Po, an isotope of polonium identified in the decay chain of radium. |
| RaC″ | Radium C″ | 81 | From radium and C″. Placeholder name given at one time to 210Tl, an isotope of thallium identified in the decay chain of radium. |
| RaD | Radium D | 82 | From radium and D. Placeholder name given at one time to 210Pb, an isotope of lead identified in the decay chain of radium. |
| RaE | Radium E | 83 | From radium and E. Placeholder name given at one time to 210Bi, an isotope of bismuth identified in the decay chain of radium. |
| RaE″ | Radium E″ | 81 | From radium and E″. Placeholder name given at one time to 206Tl, an isotope of thallium identified in the decay chain of radium. |
| RaF | Radium F | 84 | From radium and F. Placeholder name given at one time to 210Po, an isotope of polonium identified in the decay chain of radium. |
| RdAc | Radioactinium | 90 | Name given at one time to 227Th, an isotope of thorium. |
| RdTh | Radiothorium | 90 | Name given at one time to 228Th, an isotope of thorium. |
| Rn | Radon | 86 | From radium and emanation. Name restricted at one time to 222Rn, an isotope of radon identified in the decay chain of radium. This named isotope later became the official name for element 86 in 1923. |
| T | Tritium | 1 | From the Greek tritos. Name given to 3H. |
| Th | Thorium | 90 | After Thor. Name restricted at one time to 232Th, an isotope of thorium. This named isotope later became the official name for element 90. |
| ThA | Thorium A | 84 | From thorium and A. Placeholder name given at one time to 216Po, an isotope of polonium identified in the decay chain of thorium. |
| ThB | Thorium B | 82 | From thorium and B. Placeholder name given at one time to 212Pb, an isotope of lead identified in the decay chain of thorium. |
| ThC | Thorium C | 83 | From thorium and C. Placeholder name given at one time to 212Bi, an isotope of bismuth identified in the decay chain of thorium. |
| ThC′ | Thorium C′ | 84 | From thorium and C′. Placeholder name given at one time to 212Po, an isotope of polonium identified in the decay chain of thorium. |
| ThC″ | Thorium C″ | 81 | From thorium and C″. Placeholder name given at one time to 208Tl, an isotope of thallium identified in the decay chain of thorium. |
| ThX | Thorium X | 88 | Name given at one time to 224Ra, an isotope of radium identified in the decay chain of thorium. |
| Tn | Thoron | 86 | From thorium and emanation. Name given to 220Rn, an isotope of radon identified in the decay chain of thorium. |
| UI | Uranium I | 92 | Name given at one time to 238U, an isotope of uranium. |
| UII | Uranium II | 92 | Name given at one time to 234U, an isotope of uranium. |
| UX1 | Uranium X1 | 90 | Name given at one time to 234Th, an isotope of thorium identified in the decay chain of uranium. |
| UX2 | Uranium X2 | 91 | Name given at one time to 234mPa, an isotope of protactinium identified in the decay chain of uranium. |
| UY | Uranium Y | 90 | Name given at one time to 231Th, an isotope of thorium identified in the decay chain of uranium. |
| UZ | Uranium Z | 91 | Name given at one time to 234Pa, an isotope of protactinium identified in the decay chain of uranium. |
Other symbols
- In Chinese, each chemical element has a dedicated character, usually created for the purpose. However, in Chinese Latin symbols are also used, especially in formulas.
- A: A deprotonated acid or an anion
- An: any actinide
- B: A base, often in the context of Lewis acid–base theory or Brønsted–Lowry acid–base theory
- E: any element or electrophile
- L: any ligand
- Ln: any lanthanide
- M: any metal
- Mm: mischmetal
- Ng: any noble gas
- Nu: any nucleophile
- R: any unspecified radical not important to the discussion
- St: steel
- X: any halogen
- Ac: acetyl –
- Ad: 1-adamantyl
- All: allyl
- Am: amyl –
- Ar: aryl –
- Bn: benzyl
- Bs: brosyl or benzenesulfonyl
- Bu: butyl
- Bz: benzoyl
- Cp: cyclopentadienyl
- Cp*: pentamethylcyclopentadienyl
- Cy: cyclohexyl
- Cyp: cyclopentyl
- Et: ethyl
- Me: methyl
- Mes: mesityl
- Ms: mesyl
- Np: neopentyl –
- Ns: nosyl
- Pent: pentyl
- Ph, Φ: phenyl
- Pr: propyl –
- R: In organic chemistry contexts, an unspecified "R" is often understood to be an alkyl group
- Tf: triflyl
- Tr, Trt: trityl
- Ts, Tos: tosyl –
- Vi: vinyl
- Fc, ferrocenyl:
- Fp, (Cyclopentadienyl)iron dicarbonyl:
- Mu: muonium
- Pn: protonium
- Ps: positronium