John Dalton
John Dalton was an English chemist, physicist, and meteorologist whose work laid the foundations of modern atomic theory and stoichiometric chemistry. Building on earlier ideas about the indivisibility of matter and his own precise measurements of combining ratios, Dalton proposed that each chemical element consists of identical atoms of characteristic weight, and that compounds are formed when atoms of different elements combine in fixed whole-number proportions. His A New System of Chemical Philosophy presented a coherent atomic model, supplied relative atomic weights and symbolic notation, and established the quantitative framework that shaped nineteenth-century chemistry and remains the basis of modern chemical thought.
Dalton was also a pioneering meteorologist and physicist, keeping daily weather observations for over fifty years, formulating the first empirical law of partial pressures, and studying the behavior of gases through his work on vapor pressure and gas solubility. His investigations into his own color blindness led to the first scientific description of the condition—still called Daltonism in several languages—and helped establish experimental methods for linking perception with physiology. Elected a Fellow of the Royal Society in 1822 and awarded its Royal Medal in 1826, Dalton became the first British scientist to develop a quantitative atomic theory and one of the key figures in the transition of chemistry from a qualitative to a mathematical science.
In honour of Dalton's work, a unit of atomic mass, the dalton, symbol Da, is officially accepted for use with the SI.
Early life
John Dalton was born on 5 or 6 September 1766 into a Quaker family in Eaglesfield, near Cockermouth, in Cumberland, England. His father was a weaver. He received his early education from his father and from Quaker John Fletcher, who ran a private school in the nearby village of Pardshaw Hall. Dalton's family was too poor to support him for long and he began to earn his living, from the age of ten, in the service of wealthy local Quaker Elihu Robinson.Scientific work
Meteorology
Dalton's early life was influenced by a prominent Quaker, Elihu Robinson, a competent meteorologist and instrument maker, from Eaglesfield, Cumberland, who interested him in problems of mathematics and meteorology. During his years in Kendal, Dalton contributed solutions to problems and answered questions on various subjects in The Ladies' Diary and the Gentleman's Diary. In 1787 at age 21 he began his meteorological diary in which, during the succeeding 57 years, he entered more than 200,000 observations. He rediscovered George Hadley's theory of atmospheric circulation around this time. In 1793 Dalton's first publication, Meteorological Observations and Essays, contained the seeds of several of his later discoveries but despite the originality of his treatment, little attention was paid to them by other scholars. A second work by Dalton, Elements of English Grammar, was published in 1801.Measuring mountains
After leaving the Lake District, Dalton returned annually to spend his holidays studying meteorology, something which involved a lot of hill-walking. Until the advent of aeroplanes and weather balloons, the only way to make measurements of temperature and humidity at altitude was to climb a mountain. Dalton estimated the height using a barometer. The Ordnance Survey did not publish maps for the Lake District until the 1860s. Before then, Dalton was one of the few authorities on the heights of the region's mountains. He was often accompanied by Jonathan Otley, who also made a study of the heights of the local peaks, using Dalton's figures as a comparison to check his work. Otley published his information in his map of 1818. Otley became both an assistant and a friend to Dalton.Colour blindness
In 1794, shortly after his arrival in Manchester, Dalton was elected a member of the Manchester Literary and Philosophical Society, the "Lit & Phil", and a few weeks later he communicated his first paper on "Extraordinary facts relating to the vision of colours", in which he postulated that shortage in colour perception was caused by discoloration of the liquid medium of the eyeball. As both he and his brother were colour blind, he recognised that the condition must be hereditary.Although Dalton's theory was later disproven, his early research into colour vision deficiency was recognized after his lifetime. Examination of his preserved eyeball in 1995 demonstrated that Dalton had deuteranopia, a type of congenital red-green color blindness in which the gene for medium wavelength sensitive photopsins is missing. Individuals with this form of colour blindness see every colour as mapped to blue, yellow or gray, or, as Dalton wrote in his seminal paper,
Gas laws
In 1800, Dalton became secretary of the Manchester Literary and Philosophical Society, and in the following year he presented an important series of lectures, entitled "Experimental Essays" on the constitution of mixed gases; the pressure of steam and other vapours at different temperatures in a vacuum and in air; on evaporation; and on the thermal expansion of gases. The four essays, presented between 2 and 30 October 1801, were published in the Memoirs of the Literary and Philosophical Society of Manchester in 1802.The second essay opens with the remark,
After describing experiments to ascertain the pressure of steam at various points between, Dalton concluded from observations of the vapour pressure of six different liquids, that the variation of vapour pressure for all liquids is equivalent, for the same variation of temperature, reckoning from vapour of any given pressure.
In the fourth essay he remarks,
He enunciated Gay-Lussac's law, published in 1802 by Joseph Louis Gay-Lussac. In the two or three years following the lectures, Dalton published several papers on similar topics. "On the Absorption of Gases by Water and other Liquids" contained his law of partial pressures now known as Dalton's law.
Atomic theory
Arguably the most important of all Dalton's investigations are concerned with the atomic theory in chemistry. While his name is inseparably associated with this theory, the origin of Dalton's atomic theory is not fully understood. The theory may have been suggested to him either by researches on ethylene and methane or by analysis of nitrous oxide and nitrogen dioxide, both views resting on the authority of Thomas Thomson.From 1814 to 1819, Irish chemist William Higgins claimed that Dalton had plagiarised his ideas, but Higgins' theory did not address relative atomic mass. Recent evidence suggests that Dalton's development of thought may have been influenced by the ideas of another Irish chemist Bryan Higgins, who was William's uncle. Bryan believed that an atom was a heavy central particle surrounded by an atmosphere of caloric, the supposed substance of heat at the time. The size of the atom was determined by the diameter of the caloric atmosphere. Based on the evidence, Dalton was aware of Bryan's theory and adopted very similar ideas and language, but he never acknowledged Bryan's anticipation of his caloric model. However, the essential novelty of Dalton's atomic theory is that he provided a method of calculating relative atomic weights for the chemical elements, which provides the means for the assignment of molecular formulas for all chemical substances. Neither Bryan nor William Higgins did this, and Dalton's priority for that crucial innovation is uncontested.
A study of Dalton's laboratory notebooks, discovered in the rooms of the Manchester Literary and Philosophical Society, concluded that Dalton was not led by his search for an explanation of the law of multiple proportions to the idea that chemical combination consists in the interaction of atoms of definite and characteristic weight, but rather the idea of atoms arose in his mind as a purely physical concept, forced on him by study of the physical properties of the atmosphere and other gases. The first published indications of this idea are to be found at the end of his paper "On the Absorption of Gases by Water and other Liquids" already mentioned. There he says:
He then proposes relative weights for the atoms of a few elements, without going into further detail. However, a recent study of Dalton's laboratory notebook entries concludes he developed the chemical atomic theory in 1803 to reconcile Henry Cavendish's and Antoine Lavoisier's analytical data on the composition of nitric acid, not to explain the solubility of gases in water.
The main points of Dalton's atomic theory, as it eventually developed, are:
- Elements are made of extremely small particles called atoms.
- Atoms of a given element are identical in size, mass and other properties; atoms of different elements differ in size, mass and other properties.
- Atoms cannot be subdivided, created or destroyed.
- Atoms of different elements combine in simple whole-number ratios to form chemical compounds.
- In chemical reactions, atoms are combined, separated or rearranged.
This was merely an assumption, derived from faith in the simplicity of nature. No evidence was then available to scientists to deduce how many atoms of each element combine to form molecules. But this or some other such rule was absolutely necessary to any incipient theory, since one needed an assumed molecular formula in order to calculate relative atomic weights. Dalton's "rule of greatest simplicity" caused him to assume that the formula for water was OH and ammonia was NH, quite different from our modern understanding. On the other hand, his simplicity rule led him to propose the correct modern formulas for the two oxides of carbon. Despite the uncertainty at the heart of Dalton's atomic theory, the principles of the theory survived.