National Emissions Standards for Hazardous Air Pollutants


The National Emission Standards for Hazardous Air Pollutants are air pollution standards issued by the United States Environmental Protection Agency. The standards, authorized by the Clean Air Act, are for pollutants not covered by the National Ambient Air Quality Standards that may cause an increase in fatalities or in serious, irreversible, or incapacitating illness.

Maximum Achievable Control Technology standards

The standards for a particular source category require the maximum degree of emission reduction that the EPA determines to be achievable, which is known as the Maximum Achievable Control Technology standards. These standards are authorized by Section 112 of the 1970 Clean Air Act and the regulations are published in the Code of Federal Regulations.

Pollutants

EPA regulates the following hazardous air pollutants with the MACT standards.
CAS NumberChemical NameNotes
75-07-0Acetaldehyde-
60-35-5Acetamide-
75-05-8Acetonitrile-
98-86-2Acetophenone -
53-96-32-Acetylaminofluorene-
107-02-8Acrolein-
79-06-1Acrylamide-
79-10-7Acrylic acid-
107-13-1Acrylonitrile-
107-05-1Allyl chloride -
92-67-14-Aminobiphenyl-
62-53-3Aniline-
90-04-0o-Anisidine-
1332-21-4Asbestos-
71-43-2Benzeneincluding benzene from gasoline
92-87-5Benzidine-
98-07-7Benzotrichloride-
100-44-7Benzyl chloride-
92-52-4Biphenyl-
117-81-7Bis(2-ethylhexyl)phthalate -
542-88-1Bis(chloromethyl)ether-
75-25-2Bromoform -
106-99-01,3-Butadiene-
156-62-7Calcium cyanamide-
105-60-2CaprolactamDelisted on June 18, 1996
133-06-2Captan-
63-25-2Carbaryl-
75-15-0Carbon disulfide-
56-23-5Carbon tetrachloride -
463-58-1Carbonyl sulfide-
120-80-9Catechol-
133-90-4Chloramben-
57-74-9Chlordane-
7782-50-5Chlorine-
79-11-8Chloroacetic acid-
532-27-42-Chloroacetophenone-
108-90-7Chlorobenzene-
510-15-6Chlorobenzilate-
67-66-3Chloroform -
107-30-2Chloromethyl methyl ether-
126-99-8Chloroprene-
1319-77-3Cresols/Cresylic acid -
95-48-7o-Cresol-
108-39-4m-Cresol-
106-44-5p-Cresol-
98-82-8Cumene-
94-75-72,4-D, salts and esters-
3547-04-4Dichlorodiphenyldichloroethylene -
334-88-3Diazomethane-
132-64-9Dibenzofurans-
96-12-81,2-Dibromo-3-chloropropane -
84-74-2Dibutylphthalate-
106-46-71,4-Dichlorobenzene -
91-94-13,3'-Dichlorobenzidine-
111-44-4Dichloroethyl ether -
542-75-61,3-Dichloropropene-
62-73-7Dichlorvos-
111-42-2Diethanolamine-
64-67-5Diethyl sulfate-
119-90-43,3'-Dimethoxybenzidine-
60-11-7Dimethyl aminoazobenzene-
119-93-73,3'-Dimethyl benzidine-
79-44-7Dimethylcarbamoyl chloride-
68-12-2Dimethyl formamide-
57-14-71,1-Dimethyl hydrazine-
131-11-3Dimethyl phthalate-
77-78-1Dimethyl sulfate-
121-69-7N,N-DimethylanilineClean Air Act erroneously lists N,N-Diethylaniline
534-52-14,6-Dinitro-o-cresol, and salts-
51-28-52,4-Dinitrophenol-
121-14-22,4-Dinitrotoluene-
123-91-11,4-Dioxane -
122-66-71,2-Diphenylhydrazine-
106-89-8Epichlorohydrin -
106-88-71,2-Epoxybutane-
140-88-5Ethyl acrylate-
100-41-4Ethyl benzene-
51-79-6Ethyl carbamate -
75-00-3Ethyl chloride -
106-93-4Ethylene dibromide -
107-06-2Ethylene dichloride -
107-21-1Ethylene glycol-
151-56-4Ethylene imine -
75-21-8Ethylene oxide-
96-45-7Ethylene thiourea-
75-34-3Ethylidene dichloride -
50-00-0Formaldehyde-
76-44-8Heptachlor-
118-74-1Hexachlorobenzene-
87-68-3Hexachlorobutadiene-
77-47-4Hexachlorocyclopentadiene-
67-72-1Hexachloroethane-
822-06-0Hexamethylene-1,6-diisocyanate-
680-31-9Hexamethylphosphoramide-
110-54-3Hexane-
302-01-2Hydrazine-
7647-01-0Hydrochloric acid-
7664-39-3Hydrogen fluoride -
7783-06-4Hydrogen sulfideDelisted on December 4, 1991
123-31-9Hydroquinone-
78-59-1Isophorone-
58-89-9Lindane -
108-31-6Maleic anhydride-
67-56-1Methanol-
72-43-5Methoxychlor-
74-83-9Methyl bromide -
74-87-3Methyl chloride -
71-55-6Methyl chloroform -
78-93-3Methyl ethyl ketone Delisted on December 19, 2005
60-34-4Methyl hydrazine-
74-88-4Methyl iodide -
108-10-1Methyl isobutyl ketone currently under review for delisting
624-83-9Methyl isocyanate-
80-62-6Methyl methacrylate-
1634-04-4Methyl tert-butyl ether-
101-14-44,4'-Methylene bis(2-chloroaniline)-
75-09-2Methylene chloride -
101-68-8Methylene diphenyl diisocyanate currently under review for delisting
101-77-94,4'-Methylenedianiline-
91-20-3Naphthalene-
98-95-3Nitrobenzene-
92-93-34-Nitrobiphenyl-
100-02-74-Nitrophenol-
79-46-92-Nitropropane-
684-93-5N-Nitroso-N-methylurea-
62-75-9N-Nitrosodimethylamine-
59-89-2N-Nitrosomorpholine-
56-38-2Parathion-
82-68-8Pentachloronitrobenzene -
87-86-5Pentachlorophenol-
108-95-2Phenol-
106-50-3p-Phenylenediamine-
75-44-5Phosgene-
7803-51-2Phosphine-
7723-14-0Phosphorus-
85-44-9Phthalic anhydride-
1336-36-3Polychlorinated biphenyls -
1120-71-41,3-Propane sultone-
57-57-8beta-Propiolactone-
123-38-6Propionaldehyde-
114-26-1Propoxur -
78-87-5Propylene dichloride -
75-56-9Propylene oxide-
75-55-81,2-Propylenimine -
91-22-5Quinoline-
106-51-4Quinone-
100-42-5Styrene-
96-09-3Styrene oxide-
1746-01-62,3,7,8-Tetrachlorodibenzo-p-dioxin-
79-34-51,1,2,2-Tetrachloroethane-
127-18-4Tetrachloroethylene -
7550-45-0Titanium tetrachloride-
108-88-3Toluene-
95-80-72,4-Toluene diamine-
584-84-92,4-Toluene diisocyanate-
95-53-4o-Toluidine-
8001-35-2Toxaphene -
120-82-11,2,4-Trichlorobenzene-
79-00-51,1,2-Trichloroethane-
79-01-6Trichloroethylene-
95-95-42,4,5-Trichlorophenol-
88-06-22,4,6-Trichlorophenol-
121-44-8Triethylamine-
1582-09-8Trifluralin-
540-84-12,2,4-Trimethylpentane-
108-05-4Vinyl acetate-
593-60-2Vinyl bromide -
75-01-4Vinyl chloride -
75-35-4Vinylidene chloride -
1330-20-7Xylenes -
95-47-6o-Xylenes-
108-38-3m-Xylenes-
106-42-3p-Xylenes-
n/aAntimony Compounds-
n/aArsenic Compoundsinorganic including arsine
n/aBeryllium Compounds-
n/aCadmium Compounds-
n/aChromium Compounds-
n/aCobalt Compounds-
n/aCoke Oven Emissions-
n/aCyanide Compounds-
n/aGlycol ethers-
n/aLead Compounds-
n/aManganese Compounds-
n/aMercury Compounds-
n/aFine mineral fibers-
n/aNickel Compounds-
n/aPolycyclic Organic Matter-
n/aRadionuclidesincluding radon
n/aSelenium Compounds-

For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical as part of that chemical's infrastructure.

Pollution sources

Most air toxics originate from human-made sources, including mobile sources and stationary sources, as well as indoor sources. There are two types of stationary sources that generate routine emissions of air toxics:
  1. Major sources are defined as sources that emit 10 or more tons per year of any of the listed toxic air pollutants, or 25 or more tons per year of a mixture of air toxics. These sources may release air toxics from fugitive emissions, when materials are transferred from one location to another, or during discharge through emission stacks or vents.
  2. Area sources consist of smaller facilities that release lesser quantities of toxic pollutants into the air. Area sources are defined as sources that do not emit more than 10 tons per year of a single air toxic or more than 25 tons per year of a combination of air toxics. Although the emissions from individual area sources are often relatively small, collectively their emissions can be of concern, particularly where large numbers of sources are located in heavily populated areas.
EPA published its initial list of source categories in 1992. Subsequently the agency issued several revisions and updates to the list and the regulatory promulgation schedule. For each listed source category, EPA indicates whether the sources are considered to be major sources or area sources. The 1990 Clean Air Act Amendments direct EPA to set standards for all major sources of air toxics, and for some area sources that are of particular concern. EPA is required to review all source category regulations every eight years.