Tuzlaite
Tuzlaite is a borate mineral, associated with halides, named after the Tuzla salt mines in Bosnia and Hercegovina. A multitude of rare evaporate minerals have been discovered there, it being the only major evaporate deposit in the Balkans. This mineral has been approved as tuzlaite by the International Commission on New Minerals and Mineral Names.
Occurrence
Tuzlaite is found alongside several rare evaporates such as northupite, searlesite, and bradleyite. Between the layers of salt, there are approximately 50m thick layers of grey to black dolomitic marls that occasionally get cut by white veinlets composed of the mineral tuzlaite. These veinlets can be surrounded by a coronitic halite phase that can be dissolved off with H2O, leaving us with colorless to white crystals of tuzlaite up to 0.5mm in length. Most of these crystals can be intergrown, but some are suitable for X-ray single-crystal structure analysis.Physical and Optical Properties
Tuzlaite ranges from white to colorless with a perfect cleavage parallel to. The hardness of the mineral is within the range of 2 to 3 on the Mohs Hardness scale. The lustre of Tuzlaite is silky to pearly and is reliant on its growing conditions and the size of the crystal with no reaction to short-wave and long-wave UV light. Tuzalite decomposes in hydrochloric acid leaving a transparent solution with no residue, but does not react with H2O.Tuzlaite has refractive indices nx = 1.532, ny = 1.544, and nz = 1.561. The optical orientation is Y = b, Z:''a = 14°. It is optically positive with Δ = 0.029, measured with a compensator and calculated from refractive indices. The optic axial angle was measured as 2V''z = 82°; 2Vz = 80.9° was calculated from refractive indices. Indicatrix dispersion wasn't observed.
Chemistry
Tuzla mine in Bosnia-Herzegovina; average of six analyses by flamephotometry, TGA, and crystal-structure analysis; corresponds to Na1.00Σ=0.98B4.98Al0.02 O7.922 • 3H2O.NaCaB5O82 • 3H2O.