Rapakivi granite
Rapakivi granite is an igneous intrusive rock and variant of alkali feldspar granite. It is characterized by large, rounded crystals of orthoclase each with a rim of oligoclase. Common mineral components include hornblende and biotite. The name has come to be used most frequently as a textural term where it implies plagioclase rims around orthoclase in plutonic rocks. Rapakivi is a Finnish compound of "rapa" and "kivi", because the different heat expansion coefficients of the component minerals make exposed rapakivi crumble easily into sand.
Rapakivi was first described by Finnish petrologist Jakob Sederholm in 1891. Since then, southern Finland's rapakivi granite intrusions have been the type locality of this variety of granite. In the same publication, Sederholm introduced the term rapakivi texture to describe the occurrence of two generations of quartz and alkali feldspar crystals in rapakivi granites, the older alkali feldspar crystals being ovoid-shaped.
Occurrence
Rapakivi is a fairly uncommon type of granite, but has been described from localities in North and South America parts of the Baltic Shield, southern Greenland, southern Africa, India and China. Most of these examples are found within Proterozoic metamorphic belts, although both Archaean and Phanerozoic examples are known.Formation
occur in the Åland, Laitila, Vehmaa, and Wiborg batholiths. The age of the rapakivi granites of the Wiborg batholith ranges between 1646 and 1627 Ma; these granites were intruded into older metamorphic rocks. The Wiborg rapaviki granites consist of 80% wiborgite, and smaller amounts of pyterlite, porphyritic rapakivi granite, even-grained rapakivi granite, and aplitic rapakivi granite.Rapakivi granites have formation ages from Archean to recent and are usually attributed to anorogenic tectonic settings. They have formed in shallow sills of up to 10 km thickness.
Rapakivi granites are often found associated with intrusions of anorthosite, norite, charnockite and mangerite. It has been suggested that the entire suite results from the fractional crystallization of a single parental magma.
Geochemistry
Rapakivi is enriched in K, Rb, Pb, Nb, Ta, Zr, Hf, Zn, Ga, Sn, Th, U, F and rare earth elements, and poor in Ca, Mg, Al, P and Sr. Fe/Mg, K/Na and Rb/Sr ratios are high. SiO2 content is 70.5%, which makes rapakivi an acidic granite.Rapakivi is high in fluoride, ranging 0.04–1.53%, compared to other similar rocks at around 0.35%. Consequently, groundwater in rapakivi zones is high in fluoride, making the water naturally fluoridated. Some water companies actually have to remove fluoride from the water.
The uranium content of rapakivi is fairly high, up to 24 ppm. Thus, in rapakivi zones, the hazard from radon, a decay product of uranium, is elevated. Some indoor spaces surpass the 400 Bq/m3 safety limit.
Petrography
Vorma states that rapakivi granites can be defined as:- Orthoclase crystals have rounded shape
- Most orthoclase crystals have plagioclase rims
- Orthoclase and quartz have crystallized in two phases, early quartz is in tear-drop shaped crystals.
Rapakivi granites are A-type granites that, at least in the larger batholiths, have rapakivi texture.