Hardwood
Hardwood is wood from angiosperm trees. These are usually found in broad-leaved temperate and tropical forests. In temperate and boreal latitudes they are mostly deciduous, but in tropics and subtropics mostly evergreen. Hardwood contrasts with softwood.
Characteristics
Hardwoods are produced by angiosperm trees that reproduce by flowers, and have broad leaves. Many species are deciduous. Those of temperate regions lose their leaves every autumn as temperatures fall and are dormant in the winter, but those of tropical regions may shed their leaves in response to seasonal or sporadic periods of drought. Hardwood from deciduous species, such as oak, normally shows annual growth rings, but these may be absent in some tropical hardwoods.Hardwoods have a more complex structure than softwoods and are often much slower growing as a result. The dominant feature separating "hardwoods" from softwoods is the presence of pores, or vessels. The vessels may show considerable variation in size, shape of perforation plates, and structure of cell wall, such as spiral thickenings. Several specific microscopic features are used in the identification process of a hardwood species.
As the name suggests, the wood from these trees is generally harder than that of softwoods, but there are significant exceptions. In both groups there is an enormous variation in actual wood hardness, with the range in density in hardwoods completely including that of softwoods; some hardwoods are softer than most softwoods, while yew is an example of a hard softwood.
Chemistry
The structural polymers of hardwoods are cellulose, hemicellulose, and lignin. The constituents of hardwood lignin differs from those included in softwood. Sinapyl alcohol and coniferyl alcohol are the main monomers of hardwood lignin.Hardwoods contain a smaller quantity of non-structural constituents, named extractives, than softwoods. These extractives are usually categorized into three broad groups: aliphatic compounds, terpenes and phenolic compounds. Aliphatic compounds found in hardwoods include fatty acids, fatty alcohols and their esters with glycerol, fatty alcohols and sterols, hydrocarbons, such as alkanes, sterols, such as sitosterol, sitostanol and campesterol. The terpene content of the hardwood significantly differs from the softwood, and mainly consists of triterpenoids, polyprenols and other higher terpenes. Triterpenoids commonly purified from hardwoods include cycloartenol, betulin and squalene. Hardwood polyterpenes are rubber, gutta percha, gutta-balatá and betulaprenols. Although in small quantities, hardwoods also contain mono-, sesqui- and diterpenes, such as α- and β-pinenes, 3-carene, β-myrcene, limonene, hinokitiol, δ-cadinene, α- and δ-cadinols, borneol. Hardwood is rich in phenolic compounds, such as stilbenes, lignans, norlignans, tannins, flavonoids.