Coordination polymer
A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands. More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, or 3 dimensions.
It can also be described as a polymer whose repeat units are coordination complexes. Coordination polymers contain the subclass coordination networks that are coordination compounds extending, through repeating coordination entities, in 1 dimension, but with cross-links between two or more individual chains, loops, or spiro-links, or a coordination compound extending through repeating coordination entities in 2 or 3 dimensions. A subclass of these are the metal-organic frameworks, or MOFs, that are coordination networks with organic ligands containing potential voids.
Coordination polymers are relevant to many fields, having many potential applications.
Coordination polymers can be classified in a number of ways according to their structure and composition. One important classification is referred to as dimensionality. A structure can be determined to be one-, two- or three-dimensional, depending on the number of directions in space the array extends in. A one-dimensional structure extends in a straight line ; a two-dimensional structure extends in a plane ; and a three-dimensional structure extends in all three directions. This is depicted in Figure 1.
History
The work of Alfred Werner and his contemporaries laid the groundwork for the study of coordination polymers. Many time-honored materials are now recognized as coordination polymers. These include the cyanide complexes Prussian blue and Hofmann clathrates.Synthesis and propagation
Coordination polymers are often prepared by self-assembly, involving crystallization of a metal salt with a ligand. The mechanisms of crystal engineering and molecular self-assembly are relevant.The structure and dimensionality of the coordination polymer are determined by the linkers and the coordination geometry of the metal center. Coordination numbers are most often between 2 and 10. Examples of various coordination numbers are shown in planar geometry in Figure 2. In Figure 1 the 1D structure is 2-coordinated, the planar is 4-coordinated, and the 3D is 6-coordinated.
Metal centers
Metal centers, often called nodes or hubs, bond to a specific number of linkers at well defined angles. The number of linkers bound to a node is known as the coordination number, which, along with the angles they are held at, determines the dimensionality of the structure. The coordination number and coordination geometry of a metal center is determined by the nonuniform distribution of electron density around it, and in general the coordination number increases with cation size. Several models, most notably hybridization model and molecular orbital theory, use the Schrödinger equation to predict and explain coordination geometry, however this is difficult in part because of the complex effect of environment on electron density distribution.Transition metals
Transition metals are commonly used as nodes. Partially filled d orbitals, either in the atom or ion, can hybridize differently depending on environment. This electronic structure causes some of them to exhibit multiple coordination geometries, particularly copper and gold ions which as neutral atoms have full d-orbitals in their outer shells.Lanthanides
Lanthanides are large atoms with coordination numbers varying from 7 to 14. Their coordination environment can be difficult to predict, making them challenging to use as nodes. They offer the possibility of incorporating luminescent components.Alkali metals and alkaline earth metals
Alkali metals and alkaline earth metals exist as stable cations. Alkali metals readily form cations with stable valence shells, giving them different coordination behavior than lanthanides and transition metals. They are strongly affected by the counterion from the salt used in synthesis, which is difficult to avoid. The coordination polymers shown in Figure 3 are all group two metals. In this case, the dimensionality of these structures increases as the radius of the metal increases down the group.Ligands
Coordination polymers require ligands with the ability to form multiple coordination bonds, i.e. act as bridges between metal centers. Many bridging ligands are known. They range from polyfunctional heterocycles, such as pyrazine, to simple halides. Almost any type of atom with a lone pair of electrons can serve as a ligand.Very elaborate ligands have been investigated. and phosphorus, have been observed.
Structural orientation
Ligands can be flexible or rigid. A rigid ligand is one that has no freedom to rotate around bonds or reorient within a structure. Flexible ligands can bend, rotate around bonds, and reorient themselves. These different conformations create more variety in the structure. There are examples of coordination polymers that include two configurations of the same ligand within one structure, as well as two separate structures where the only difference between them is ligand orientation.Ligand length
A length of the ligand can be an important factor in determining possibility for formation of a polymeric structure versus non-polymeric structures.Other factors
Counterion
Besides metal and ligand choice, there are many other factors that affect the structure of the coordination polymer. For example, most metal centers are positively charged ions which exist as salts. The counterion in the salt can affect the overall structure. For example, when silver salts such as AgNO3, AgBF4, AgClO4, AgPF6, AgAsF6 and AgSbF6 are all crystallized with the same ligand, the structures vary in terms of the coordination environment of the metal, as well as the dimensionality of the entire coordination polymer.Crystallization environment
Additionally, variations in the crystallization environment can also change the structure. Changes in pH, exposure to light, or changes in temperature can all change the resulting structure. Influences on the structure based on changes in crystallization environment are determined on a case by case basis.Guest molecules
The structure of coordination polymers often incorporates empty space in the form of pores or channels. This empty space is thermodynamically unfavorable. In order to stabilize the structure and prevent collapse, the pores or channels are often occupied by guest molecules. Guest molecules do not form bonds with the surrounding lattice, but sometimes interact via intermolecular forces, such as hydrogen bonding or pi stacking. Most often, the guest molecule will be the solvent that the coordination polymer was crystallized in, but can really be anything The presence of the guest molecule can sometimes influence the structure by supporting a pore or channel, where otherwise none would exist.Applications
Coordination polymers are found in some commercialized as dyes.. Metal complex dyes using copper or chromium are commonly used for producing dull colors. Tridentate ligand dyes are useful because they are more stable than their bi- or mono-dentate counterparts.350px
Some early commercialized coordination polymers are the Hofmann compounds, which have the formula Ni4Ni2. These materials crystallize with small aromatic guests, and this selectivity has been exploited commercially for the separation of these hydrocarbons.
Research trends
Molecular storage
Although not yet practical, porous coordination polymers have potential as molecular sieves in parallel with porous carbon and zeolites. The size and shapes of the pore can be controlled by the linker size and the connecting ligands' length and functional groups. To modify the pore size in order to achieve effective adsorption, nonvolatile guests are intercalated in the porous coordination polymer space to decrease the pore size. Active surface guests can also be used contribute to adsorption. For example, the large-pore MOF-177, 11.8 Å in diameter, can be doped by C60 molecules or polymers with a highly conjugated system in order to increase the surface area for H2 adsorption.Flexible porous coordination polymers are potentially attractive for molecular storage, since their pore sizes can be altered by physical changes. An example of this might be seen in a polymer that contains gas molecules in its normal state, but upon compression the polymer collapses and releases the stored molecules. Depending on the structure of the polymer, it is possible that the structure be flexible enough that collapsing the pores is reversible and the polymer can be reused to uptake the gas molecules again. The Metal-organic framework page has a detailed section dealing with H2 gas storage.