Thorium fuel cycle
The thorium fuel cycle is a nuclear fuel cycle that uses an isotope of thorium,, as the fertile material. In the reactor, is transmuted into the fissile artificial uranium isotope which is the nuclear fuel. Unlike natural uranium, natural thorium contains only trace amounts of fissile material, which are insufficient to initiate a nuclear chain reaction. Additional fissile material or another neutron source is necessary to initiate the fuel cycle. In a thorium-fuelled reactor, absorbs neutrons to produce. This parallels the process in uranium breeder reactors whereby fertile absorbs neutrons to form fissile. Depending on the design of the reactor and fuel cycle, the generated either fissions in situ or is chemically separated from the used nuclear fuel and formed into new nuclear fuel.
The thorium fuel cycle has several potential advantages over a uranium fuel cycle, including thorium's greater abundance, superior physical and nuclear properties, reduced plutonium and actinide production, and better resistance to nuclear weapons proliferation when used in a traditional light water reactor though not in a molten salt reactor.
History
Concerns about the limits of worldwide uranium resources motivated initial interest in the thorium fuel cycle. It was envisioned that as uranium reserves were depleted, thorium would supplement uranium as a fertile material. However, for most countries uranium was relatively abundant and research in thorium fuel cycles waned. A notable exception was India's three-stage nuclear power programme.In the twenty-first century thorium's claimed potential for improving proliferation resistance and waste characteristics led to renewed interest in the thorium fuel cycle. While thorium is more abundant in the continental crust than uranium and easily extracted from monazite as a side product of rare earth element mining, it is much less abundant in seawater than uranium.
At Oak Ridge National Laboratory in the 1960s, the Molten-Salt Reactor Experiment used as the fissile fuel in an experiment to demonstrate a part of the Molten Salt Breeder Reactor that was designed to operate on the thorium fuel cycle. Molten salt reactor experiments assessed thorium's feasibility, using thorium fluoride dissolved in a molten salt fluid that eliminated the need to fabricate fuel elements. The MSR program was defunded in 1976 after its patron Alvin Weinberg was fired.
In 1993, Carlo Rubbia proposed the concept of an energy amplifier or "accelerator driven system", which he saw as a novel and safe way to produce nuclear energy that exploited existing accelerator technologies. Rubbia's proposal offered the potential to incinerate high-activity nuclear waste and produce energy from natural thorium and depleted uranium.
Kirk Sorensen, former NASA scientist and Chief Technologist at Flibe Energy, has been a long-time promoter of thorium fuel cycle and particularly liquid fluoride thorium reactors. He first researched thorium reactors while working at NASA, while evaluating power plant designs suitable for lunar colonies. In 2006 Sorensen started "energyfromthorium.com" to promote and make information available about this technology.
A 2011 MIT study concluded that although there is little in the way of barriers to a thorium fuel cycle, with current or near term light-water reactor designs there is also little incentive for any significant market penetration to occur. As such they conclude there is little chance of thorium cycles replacing conventional uranium cycles in the current nuclear power market, despite the potential benefits.
Nuclear reactions with thorium
In the thorium cycle, fuel is formed when captures a neutron to become. This normally emits an electron and an anti-neutrino by decay to become. This then emits another electron and anti-neutrino by a second decay to become, the fuel:Fission product waste
produces radioactive fission products which can have half-lives from days to greater than 200,000 years. According to some toxicity studies, the thorium cycle can fully recycle actinide wastes and only emit fission product wastes, and after a few hundred years, the waste from a thorium reactor can be less toxic than the uranium ore that would have been used to produce low enriched uranium fuel for a light water reactor of the same power.Other studies assume some actinide losses and find that actinide wastes dominate thorium cycle waste radioactivity at some future periods. Some fission products have been proposed for nuclear transmutation, which would further reduce the amount of nuclear waste and the duration during which it would have to be stored. However, while the principal feasibility of some of those reactions has been demonstrated at laboratory scale, there is, as of 2024, no large scale deliberate transmutation of fission products anywhere in the world, and the upcoming MYRRHA research project into transmutation is mostly focused on transuranic waste. Furthermore, the cross section of some fission products is relatively low and others - such as caesium - are present as a mixture of stable, short lived and long lived isotopes in nuclear waste, making transmutation dependent on expensive isotope separation.
Actinide waste
In a reactor, when a neutron hits a fissile atom, it either splits the nucleus or is captured and transmutes the atom. In the case of, the transmutations tend to produce useful nuclear fuels rather than transuranic waste. When absorbs a neutron, it either fissions or becomes. The chance of fissioning on absorption of a thermal neutron is about 92%; the capture-to-fission ratio of, therefore, is about 1:12 – which is better than the corresponding capture vs. fission ratios of , or or . The result is less transuranic waste than in a reactor using the uranium-plutonium fuel cycle., like most actinides with an even number of neutrons, is not fissile, but neutron capture produces fissile. If the fissile isotope fails to fission on neutron capture, it produces,,, and eventually fissile and heavier isotopes of plutonium. The can be removed and stored as waste or retained and transmuted to plutonium, where more of it fissions, while the remainder becomes, then americium and curium, which in turn can be removed as waste or returned to reactors for further transmutation and fission.
However, the formed via reactions with , while not a transuranic waste, is a major contributor to the long-term radiotoxicity of spent nuclear fuel. While can in principle be converted back to by neutron absorption, its neutron absorption cross section is relatively low, making this rather difficult and possibly uneconomic.
Uranium-232 contamination
is also formed in this process, via reactions between fast neutrons and,, and :Unlike most even numbered heavy isotopes, is also a fissile fuel fissioning just over half the time when it absorbs a thermal neutron. has a relatively short half-life, and some decay products emit high energy gamma radiation, such as, and particularly. The full decay chain, along with half-lives and relevant gamma energies, is:
decays to where it joins the decay chain of
Thorium-cycle fuels produce hard gamma emissions, which damage electronics, limiting their use in bombs. cannot be chemically separated from from used nuclear fuel; however, chemical separation of thorium from uranium removes the decay product and the radiation from the rest of the decay chain, which gradually build up as reaccumulates. The contamination could also be avoided by using a molten-salt breeder reactor and separating the before it decays into. The hard gamma emissions also create a radiological hazard which requires remote handling during reprocessing.
Nuclear fuel
As a fertile material thorium is similar to, the major part of natural and depleted uranium. The thermal neutron absorption cross section and resonance integral for are about three and one third times those of the respective values for.Advantages
The primary physical advantage of thorium fuel is that it uniquely makes possible a breeder reactor that runs with slow neutrons, otherwise known as a thermal breeder reactor. These reactors are often considered simpler than the more traditional fast-neutron breeders. Although the thermal neutron fission cross section of the resulting is comparable to and, it has a much lower capture cross section than the latter two fissile isotopes, providing fewer non-fissile neutron absorptions and improved neutron economy. The ratio of neutrons released per neutron absorbed in is greater than two over a wide range of energies, including the thermal spectrum. A breeding reactor in the uranium–plutonium cycle needs to use fast neutrons, because in the thermal spectrum one neutron absorbed by on average leads to less than two neutrons.Thorium is estimated to be about three to four times more abundant than uranium in Earth's crust, although present knowledge of reserves is limited. Current demand for thorium has been satisfied as a by-product of rare-earth extraction from monazite sands. Notably, there is very little thorium dissolved in seawater, so seawater extraction is not viable, as it is with uranium. Using breeder reactors, known thorium and uranium resources can both generate world-scale energy for thousands of years.
Thorium-based fuels also display favorable physical and chemical properties that improve reactor and repository performance. Compared to the predominant reactor fuel, uranium dioxide, thorium dioxide has a higher melting point, higher thermal conductivity, and lower coefficient of thermal expansion. Thorium dioxide also exhibits greater chemical stability and, unlike uranium dioxide, does not further oxidize.
Because the produced in thorium fuels is significantly contaminated with in proposed power reactor designs, thorium-based used nuclear fuel possesses inherent proliferation resistance. cannot be chemically separated from and has several decay products that emit high-energy gamma radiation. These high-energy photons are a radiological hazard that necessitate the use of remote handling of separated uranium and aid in the passive detection of such materials.
The long-term radiological hazard of conventional uranium-based used nuclear fuel is dominated by plutonium and other minor actinides, after which long-lived fission products become significant contributors again. A single neutron capture in is sufficient to produce transuranic elements, whereas five captures are generally necessary to do so from. 98–99% of thorium-cycle fuel nuclei would fission at either or, so fewer long-lived transuranics are produced. Because of this, thorium is a potentially attractive alternative to uranium in mixed oxide fuels to minimize the generation of transuranics and maximize the destruction of plutonium.