Spinor spherical harmonics
In quantum mechanics, the spinor spherical harmonics are special functions defined over the sphere. The spinor spherical harmonics are the natural spinor analog of the vector spherical harmonics. While the standard spherical harmonics are a basis for the angular [momentum operator], the spinor spherical harmonics are a basis for the total angular momentum operator. These functions are used in analytical solutions to Dirac equation in a radial potential. The spinor spherical harmonics are sometimes called Pauli central field spinors, in honor of Wolfgang Pauli who employed them in the solution of the hydrogen atom with spin–orbit interaction.
Properties
The spinor spherical harmonics are the spinors eigenstates of the total angular momentum operator squared:where, where,, and are the total, orbital and spin angular momentum operators, j is the total azimuthal quantum number and m is the total magnetic quantum number.
Under a parity operation, we have
For spin-1/2 systems, they are given in matrix form by
where are the usual spherical harmonics.