In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when one of the solvents is water.
- A solution is a homogeneous mixture of two or more substances.
- The particles of solute in a solution cannot be seen by the naked eye.
- A solution does not allow beams of light to scatter.
- A solution is stable.
- The solute from a solution cannot be separated by filtration.
- It is composed of only one phase.
Gaseous solutionsIf the solvent is a gas, only gases are dissolved under a given set of conditions. An example of a gaseous solution is air. Since interactions between molecules play almost no role, dilute gases form rather trivial solutions. In part of the literature, they are not even classified as solutions, but addressed as mixtures.
Liquid solutionsIf the solvent is a liquid, then almost all gases, liquids, and solids can be dissolved. Here are some examples:
- Gas in liquid:
- * Oxygen in water
- * Carbon dioxide in water – a less simple example, because the solution is accompanied by a chemical reaction. The visible bubbles in carbonated water are not the dissolved gas, but only an effervescence of carbon dioxide that has come out of solution; the dissolved gas itself is not visible since it is dissolved on a molecular level.
- Liquid in liquid:
- * The mixing of two or more substances of the same chemistry but different concentrations to form a constant.
- * Alcoholic beverages are basically solutions of ethanol in water.
- Solid in liquid:
- * Sucrose in water
- * Sodium chloride or any other salt in water, which forms an electrolyte: When dissolving, salt dissociates into ions.
- Solutions in water are especially common, and are called aqueous solutions.
- Non-aqueous solutions are when the liquid solvent involved is not water.
Body fluids are examples for complex liquid solutions, containing many solutes. Many of these are electrolytes, since they contain solute ions, such as potassium. Furthermore, they contain solute molecules like sugar and urea. Oxygen and carbon dioxide are also essential components of blood chemistry, where significant changes in their concentrations may be a sign of severe illness or injury.
Solid solutionsIf the solvent is a solid, then gases, liquids and solids can be dissolved.
- Gas in solids:
- * Hydrogen dissolves rather well in metals, especially in palladium; this is studied as a means of hydrogen storage.
- Liquid in solid:
- * Mercury in gold, forming an amalgam
- * Water in solid salt or sugar, forming moist solids
- * Hexane in paraffin wax
- Solid in solid:
- * Steel, basically a solution of carbon atoms in a crystalline matrix of iron atoms
- * Alloys like bronze and many others
- * Polymers containing plasticizers
All solutions have a positive entropy of mixing. The interactions between different molecules or ions may be energetically favored or not. If interactions are unfavorable, then the free energy decreases with increasing solute concentration. At some point the energy loss outweighs the entropy gain, and no more solute particles can be dissolved; the solution is said to be saturated. However, the point at which a solution can become saturated can change significantly with different environmental factors, such as temperature, pressure, and contamination. For some solute-solvent combinations a supersaturated solution can be prepared by raising the solubility to dissolve more solute, and then lowering it.
Usually, the greater the temperature of the solvent, the more of a given solid solute it can dissolve. However, most gases and some compounds exhibit solubilities that decrease with increased temperature. Such behavior is a result of an exothermic enthalpy of solution. Some surfactants exhibit this behaviour. The solubility of liquids in liquids is generally less temperature-sensitive than that of solids or gases.
PropertiesThe physical properties of compounds such as melting point and boiling point change when other compounds are added. Together they are called colligative properties. There are several ways to quantify the amount of one compound dissolved in the other compounds collectively called concentration. Examples include molarity, volume fraction, and mole fraction.
The properties of ideal solutions can be calculated by the linear combination of the properties of its components. If both solute and solvent exist in equal quantities, the concepts of "solute" and "solvent" become less relevant, but the substance that is more often used as a solvent is normally designated as the solvent.
LiquidIn principle, all types of liquids can behave as solvents: liquid noble gases, molten metals, molten salts, molten covalent networks, and molecular liquids. In the practice of chemistry and biochemistry, most solvents are molecular liquids. They can be classified into polar and non-polar, according to whether their molecules possess a permanent electric dipole moment. Another distinction is whether their molecules can form hydrogen bonds. Water, the most commonly used solvent, is both polar and sustains hydrogen bonds.
is a good solvent because the molecules are polar and capable of forming hydrogen bonds.
Salts dissolve in polar solvents, forming positive and negative ions that are attracted to the negative and positive ends of the solvent molecule, respectively. If the solvent is water, hydration occurs when the charged solute ions become surrounded by water molecules. A standard example is aqueous saltwater. Such solutions are called electrolytes. Whenever salt dissolves in water ion association has to be taken into account.
Polar solutes dissolve in polar solvents, forming polar bonds or hydrogen bonds. As an example, all alcoholic beverages are aqueous solutions of ethanol. On the other hand, non-polar solutes dissolve better in non-polar solvents. Examples are hydrocarbons such as oil and grease that easily mix with each other, while being incompatible with water.
An example for the immiscibility of oil and water is a leak of petroleum from a damaged tanker, that does not dissolve in the ocean water but rather floats on the surface.
Preparation from constituent ingredientsIt is common practice in laboratories to make a solution directly from its constituent ingredients. There are three cases in practical calculation:
- Case 1: amount of solvent volume is given.
- Case 2: amount of solute mass is given.
- Case 3: amount of final solution volume is given.
- Case 1: amount of solvent volume VA is given. Solute mass mB = C VA dA /
- Case 2: amount of solute mass mB is given. Solvent volume VA = mB
- Case 3: amount of final solution volume Vt is given. Solute mass mB = C Vt /100; Solvent volume VA= mB
- Case 2: solute mass is known, VA = mB 100/C
- Case 3: total solution volume is known, same equation as case 1. VA=Vt; mB = C VA /100