Mole fraction
In chemistry, the mole fraction or molar fraction, also called mole proportion or molar proportion, is a quantity defined as the ratio between the amount of a constituent substance, ni, and the total amount of all constituents in a mixture, ntot :
It is denoted xi, sometimes .
It is a dimensionless quantity with dimension of and dimensionless unit of moles per mole or simply 1; metric prefixes may also be used.
When expressed in percent, it is known as the mole percent or molar percentage.
The mole fraction is called amount fraction by the International Union of Pure and Applied Chemistry and amount-of-substance fraction by the U.S. National Institute of Standards and Technology. This nomenclature is part of the International System of Quantities, as standardized in ISO 80000-9, which deprecates "mole fraction" based on the unacceptability of mixing information with units when expressing the values of quantities.
The sum of all the mole fractions in a mixture is equal to 1:
Mole fraction is numerically identical to the number fraction, which is defined as the number of particles of a constituent Ni divided by the total number of all molecules Ntot.
Whereas mole fraction is a ratio of amounts to amounts, molar concentration is a quotient of amount to volume.
Other ways of expressing the composition of a mixture as a dimensionless quantity are mass fraction and volume fraction.
Properties
Mole fraction is used very frequently in the construction of phase diagrams. It has a number of advantages:- it is not temperature dependent and does not require knowledge of the densities of the phase involved
- a mixture of known mole fraction can be prepared by weighing off the appropriate masses of the constituents
- the measure is symmetric: in the mole fractions x = 0.1 and x = 0.9, the roles of 'solvent' and 'solute' are reversed.
- In a mixture of ideal gases, the mole fraction can be expressed as the ratio of partial pressure to total pressure of the mixture
- In a ternary mixture one can express mole fractions of a component as functions of other components mole fraction and binary mole ratios:
- :
or
The ratios X, Y, and Z of mole fractions can be written for ternary and multicomponent systems:
These can be used for solving PDEs like:
or
This equality can be rearranged to have differential quotient of mole amounts or fractions on one side.
or
Mole amounts can be eliminated by forming ratios:
Thus the ratio of chemical potentials becomes:
Similarly the ratio for the multicomponents system becomes
Related quantities
Mass fraction
The mass fraction wi can be calculated using the formulawhere Mi is the molar mass of the component i and M̄ is the average molar mass of the mixture.
Molar mixing ratio
The mixing of two pure components can be expressed introducing the amount or molar mixing ratio of them. Then the mole fractions of the components will be:The amount ratio equals the ratio of mole fractions of components:
due to division of both numerator and denominator by the sum of molar amounts of components. This property has consequences for representations of phase diagrams using, for instance, ternary plots.
Mixing binary mixtures with a common component to form ternary mixtures
Mixing binary mixtures with a common component gives a ternary mixture with certain mixing ratios between the three components. These mixing ratios from the ternary and the corresponding mole fractions of the ternary mixture x1, x2, x3 can be expressed as a function of several mixing ratios involved, the mixing ratios between the components of the binary mixtures and the mixing ratio of the binary mixtures to form the ternary one.Mole percentage
Multiplying mole fraction by 100 gives the mole percentage, also referred as amount/amount percent .Mass concentration
The conversion to and from mass concentration ρi is given by:where M̄ is the average molar mass of the mixture.
Molar concentration
The conversion to molar concentration ci is given by:where M̄ is the average molar mass of the solution, c is the total molar concentration and ρ is the density of the solution.