Mandelin reagent


The Mandelin reagent is used as a simple spot-test to presumptively identify alkaloids as well as other compounds. It is composed of a mixture of ammonium metavanadate and concentrated sulfuric acid. Its primary use is for the detection of ketamine and PMA Unlike the most common reagent test chemicals, it has a deep red colour that changes to yellow if there is no alkaloid, which occurs within about 48 hours of mixing.
The United States Department of Justice method for producing the reagent is the addition of 100 mL of concentrated sulfuric acid to 0.5-1 g of ammonium metavanadate.
This reagent was invented by the German pharmacologist, Karl Friedrich Mandelin at the Imperial University of Dorpat.
SubstanceColor
2C-T-7Wine dark to Black
AcetaminophenModerate olive
BenzphetamineBrilliant yellow green
ChlorpromazineDark olive
CocaineDeep orange yellow
CodeineDark olive
d-AmphetamineModerate bluish green
d-MethamphetamineDark yellowish green
Diacetylmorphine Moderate reddish brown
DimethoxymethamphetamineDark olive brown
DoxepinVery reddish brown
DristanGreyish olive
ExedrineDark olive
KetamineDeep reddish orange
MaceModerate olive green
MDABluish black
MDMABluish black
MescalineDark yellowish brown
MethadoneDark greyish blue
MethaqualoneVery orange yellow
MethylphenidateBrilliant orange yellow
MorphineDark greyish reddish brown
OpiumOlive black
OxycodoneDark greenish yellow
ProcaineDeep orange
PropoxypheneDark reddish brown
PsilocybinGreen
Paramethoxyamphetamine Reddish brown
Paramethoxymethamphetamine Reddish brown
Salt Strong orange