| Office | Name | Date |
First Lord of the Treasury Leader of the House of Lords | Robert Jenkinson, 2nd Earl of Liverpool | 8 June 1812 – 9 April 1827 |
| Chancellor of the Exchequer | Nicholas Vansittart | 9 June 1812 |
| Chancellor of the Exchequer | Frederick Robinson | 21 January 1823 |
| Secretaries to the Treasury | Richard Wharton | Continued in office – 1814 |
| Secretaries to the Treasury | Charles Arbuthnot | Continued in office – 1823 |
| Secretaries to the Treasury | Stephen Rumbold Lushington | 1814–1827 |
| Secretaries to the Treasury | John Charles Herries | 1823–1827 |
| Junior Lords of the Treasury | William Vesey-FitzGerald | 16 June 1812 – 7 January 1817 |
| Junior Lords of the Treasury | Berkeley Paget | 16 June 1812 – 13 June 1826 |
| Junior Lords of the Treasury | Frederick Robinson | 16 June 1812 – 25 November 1813 |
| Junior Lords of the Treasury | James Brogden | 16 June 1812 – 20 December 1813 |
| Junior Lords of the Treasury | William Lowther, Viscount Lowther | 25 November 1813 – 30 April 1827 |
| Junior Lords of the Treasury | Charles Grant | 20 December 1813 – 25 March 1819 |
| Junior Lords of the Treasury | John Maxwell-Barry | 7 January 1817 – 3 May 1823 |
| Junior Lords of the Treasury | William Odell | 7 January 1817 – 25 March 1819 |
| Junior Lords of the Treasury | Lord Granville Somerset | 25 March 1819 – 30 April 1827 |
| Junior Lords of the Treasury | Edmond Alexander Macnaghten | 25 March 1819 – 30 April 1827 |
| Junior Lords of the Treasury | Francis Conyngham, Earl of Mount Charles | 13 June 1826 – 30 April 1827 |
| Lord Chancellor | John Scott, 1st Baron Eldon | Continued in office |
| Lord President of the Council | Dudley Ryder, 1st Earl of Harrowby | 11 June 1812 |
| Lord Privy Seal | John Fane, 10th Earl of Westmorland | Continued in office |
| Home Secretary | Henry Addington, 1st Viscount Sidmouth | 11 June 1812 |
| Home Secretary | Robert Peel | 17 January 1822 |
| Under-Secretary of State for the Home Department | Henry Goulburn | Continued in office |
| Under-Secretary of State for the Home Department | John Hiley Addington | August 1812 |
| Under-Secretary of State for the Home Department | Henry Clive | April 1818 |
| Under-Secretary of State for the Home Department | George Robert Dawson | January 1822 |
Secretary of State for Foreign Affairs Leader of the House of Commons | Robert Stewart, Viscount Castlereagh | Continued in office |
Secretary of State for Foreign Affairs Leader of the House of Commons | George Canning | 16 September 1822 |
| Under-Secretary of State for Foreign Affairs | Edward Cooke | Continued in office |
| Under-Secretary of State for Foreign Affairs | Joseph Planta | 25 July 1817 |
| Under-Secretary of State for Foreign Affairs | Richard Meade, 3rd Earl of Clanwilliam | 22 January 1822 |
| Under-Secretary of State for Foreign Affairs | Lord Francis Conyngham | January 1823 – January 1826 |
| Under-Secretary of State for Foreign Affairs | Charles Ellis, 6th Baron Howard de Walden | July 1824 – April 1827 |
| Under-Secretary of State for Foreign Affairs | Ulick de Burgh, 1st Marquess of Clanricarde | January 1826 – April 1827 |
| Secretary of State for War and the Colonies | Henry Bathurst, 3rd Earl Bathurst | 11 June 1812 |
| Under-Secretary of State for War and the Colonies | Henry Bunbury | Continued in office – 1816 |
| Under-Secretary of State for War and the Colonies | Robert Peel | Continued in office – 1812 |
| Under-Secretary of State for War and the Colonies | Henry Goulburn | 1812–1821 |
| Under-Secretary of State for War and the Colonies | Robert Wilmot Horton | 1821 |
| First Lord of the Admiralty | Robert Dundas, 2nd Viscount Melville | Continued in office |
| First Secretary to the Admiralty | John Wilson Croker | Continued in office |
| Civil Lords of the Admiralty | Frederick Robinson | Continued in office – 5 October 1812 |
| Civil Lords of the Admiralty | Horatio Walpole, Baron Walpole | Continued in office – 5 October 1812 |
| Civil Lords of the Admiralty | William Dundas | Continued in office – 23 August 1814 |
| Civil Lords of the Admiralty | Sir George Warrender, 4th Baronet | 5 October 1812 – 8 February 1822 |
| Civil Lords of the Admiralty | John Osborn | 5 October 1812 – 16 February 1824 |
| Civil Lords of the Admiralty | Henry Somerset, Marquess of Worcester | 24 May 1816 – 15 March 1819 |
| Civil Lords of the Admiralty | Sir George Clerk, 6th Baronet | 15 March 1819 – 2 May 1827 |
| Civil Lords of the Admiralty | Lord William Douglas | 8 February – 23 March 1822 16 February 1824 – 2 May 1827 |
| President of the Board of Trade | Henry Bathurst, 3rd Earl Bathurst | Continued in office |
| President of the Board of Trade | Richard Le Poer Trench, 2nd Earl of Clancarty | 29 September 1812 |
| President of the Board of Trade | Frederick Robinson | 24 January 1818 |
| President of the Board of Trade | William Huskisson | 31 January 1823 |
| Vice-President of the Board of Trade | George Rose | Continued in office |
| Vice-President of the Board of Trade | Frederick Robinson | 29 September 1812 |
| Vice-President of the Board of Trade | Thomas Wallace | 24 January 1818 |
| Vice-President of the Board of Trade | Charles Grant | 3 April 1823 |
| President of the Board of Control | Robert Hobart, 4th Earl of Buckinghamshire | Continued in office |
| President of the Board of Control | George Canning | 20 June 1816 |
| President of the Board of Control | Charles Bragge Bathurst | 16 January 1821 |
| President of the Board of Control | Charles Williams-Wynn | 8 February 1822 |
| Secretary to the Board of Control | John Bruce | Continued in office |
| Secretary to the Board of Control | Thomas Courtenay | 20 August 1812 |
| Chancellor of the Duchy of Lancaster | Robert Hobart, 4th Earl of Buckinghamshire | 23 June 1812 |
| Chancellor of the Duchy of Lancaster | Charles Bathurst | 23 August 1812 |
| Chancellor of the Duchy of Lancaster | Nicholas Vansittart | 13 February 1823 |
| Master-General of the Ordnance | Henry Phipps, 1st Earl of Mulgrave | Continued in office |
| Master-General of the Ordnance | Arthur Wellesley, 1st Duke of Wellington | 1 January 1819 |
| Lieutenant-General of the Ordnance | Sir Thomas Trigge | Continued in office – 11 January 1814 |
| Lieutenant-General of the Ordnance | Sir Hildebrand Oakes, 1st Baronet | 9 March 1814 – 9 September 1822 |
| Lieutenant-General of the Ordnance | William Beresford, 1st Viscount Beresford | 18 February 1823 |
| Lieutenant-General of the Ordnance | Sir George Murray | 22 March 1824 |
| Lieutenant-General of the Ordnance | Sir William Henry Clinton | 30 April 1825 |
| Treasurer of the Ordnance | Thomas Alcock | Continued in office |
| Treasurer of the Ordnance | William Holmes | 20 June 1818 |
| Surveyor-General of the Ordnance | Robert Moorsom | Continued in office |
| Surveyor-General of the Ordnance | Sir Ulysses Burgh | 16 March 1820 |
| Clerk of the Ordnance | Robert Plumer Ward | Continued in office |
| Clerk of the Ordnance | Sir Henry Hardinge | 29 April 1823 |
| Clerk of the Deliveries of the Ordnance | Thomas Thoroton | Continued in office |
| Clerk of the Deliveries of the Ordnance | Edmund Phipps | 31 October 1812 |
| Storekeeper of the Ordnance | Mark Singleton | Continued in office |
| Treasurer of the Navy | George Rose | Continued in office |
| Treasurer of the Navy | Frederick Robinson | 12 February 1818 |
| Treasurer of the Navy | William Huskisson | 8 February 1823 |
| Secretary at War | Henry John Temple, 3rd Viscount Palmerston | Continued in office |
| Master of the Mint | Henry Bathurst, 3rd Earl Bathurst | Continued in office |
| Master of the Mint | Richard Le Poer Trench, 2nd Earl of Clancarty | 30 October 1812 |
| Master of the Mint | William Wellesley-Pole | 28 September 1814 |
| Master of the Mint | Thomas Wallace | 9 October 1823 |
| Paymaster of the Forces | Charles Long | Continued in office – 1826 |
| Paymaster of the Forces | Lord Charles Henry Somerset | Continued in office – 1813 |
| Paymaster of the Forces | Frederick Robinson | 9 November 1813 – 1817 |
| Paymaster of the Forces | William Vesey-FitzGerald | 1826 |
| Postmaster General | Thomas Pelham, 2nd Earl of Chichester | Continued in office – 1826 |
| Postmaster General | John Montagu, 5th Earl of Sandwich | Continued in office – 1814 |
| Postmaster General | Richard Trench, 2nd Earl of Clancarty | 1814–1816 |
| Postmaster General | James Cecil, 1st Marquess of Salisbury | 1816–1823 |
| Postmaster General | Lord Frederick Montagu | 1826–1827 |
| First Commissioner of Woods and Forests | Sylvester Douglas, 1st Baron Glenbervie | Continued in office |
| First Commissioner of Woods and Forests | William Huskisson | 1814 |
| First Commissioner of Woods and Forests | Charles Arbuthnot | 1823 |
| Minister without Portfolio | John Pratt, 1st Earl Camden | June 1812 – December 1812 |
| Minister without Portfolio | Henry Phipps, 1st Earl of Mulgrave | January 1819 – May 1820 |
| Lord Lieutenant of Ireland | Charles Lennox, 4th Duke of Richmond | Continued in office |
| Lord Lieutenant of Ireland | Charles Whitworth, 1st Earl Whitworth | June 1813 |
| Lord Lieutenant of Ireland | Charles Chetwynd-Talbot, 2nd Earl Talbot | October 1817 |
| Lord Lieutenant of Ireland | Richard Wellesley, 1st Marquess Wellesley | December 1821 |
| Chief Secretary for Ireland | William Wellesley-Pole | Continued in office |
| Chief Secretary for Ireland | Robert Peel | August 1812 |
| Chief Secretary for Ireland | Charles Grant | August 1818 |
| Chief Secretary for Ireland | Henry Goulburn | December 1821 |
| Attorney General | Sir Thomas Plumer | 26 June 1812 |
| Attorney General | Sir William Garrow | 4 May 1813 |
| Attorney General | Sir Samuel Shepherd | 7 May 1817 |
| Attorney General | Sir Robert Gifford | 24 July 1819 |
| Attorney General | Sir John Copley | 9 January 1824 |
| Attorney General | Sir Charles Wetherell | 20 September 1826 |
| Solicitor General | Sir William Garrow | 26 June 1812 |
| Solicitor General | Sir Robert Dallas | 4 May 1813 |
| Solicitor General | Sir Samuel Shepherd | 22 December 1813 |
| Solicitor General | Sir Robert Gifford | 7 May 1817 |
| Solicitor General | Sir John Copley | 24 July 1819 |
| Solicitor General | Sir Charles Wetherell | 9 January 1824 |
| Solicitor General | Sir Nicholas Conyngham Tindal | 20 September 1826 |
| Judge Advocate General | Charles Manners-Sutton | Continued in office |
| Judge Advocate General | Sir John Beckett, 2nd Baronet | 25 June 1817 |
| Lord Advocate | Archibald Colquhoun | Continued in office |
| Lord Advocate | Alexander Maconochie | 1816 |
| Lord Advocate | Sir William Rae, 3rd Baronet | 1819 |
| Solicitor General for Scotland | David Monypenny | Continued in office |
| Solicitor General for Scotland | Alexander Maconochie | 1813 |
| Solicitor General for Scotland | James Wedderburn | 1816 |
| Solicitor General for Scotland | John Hope | 1822 |
| Attorney General for Ireland | William Conyngham Plunket | 1822 |
| Solicitor General for Ireland | Charles Kendal Bushe | Continued in office |
| Solicitor General for Ireland | Henry Joy | 20 February 1822 |
| Lord Steward of the Household | George Cholmondeley, 4th Earl of Cholmondeley | Continued in office |
| Lord Steward of the Household | Henry Conyngham, 1st Marquess Conyngham | 11 December 1821 |
| Treasurer of the Household | Robert Jocelyn, Viscount Jocelyn | Continued in office |
| Treasurer of the Household | Lord Charles Bentinck | 29 July 1812 |
| Treasurer of the Household | William Henry Fremantle | 27 May 1826 |
| Comptroller of the Household | Lord George Thynne | Continued in office |
| Comptroller of the Household | Lord George Beresford | 29 July 1812 |
| Lord Chamberlain of the Household | Francis Ingram-Seymour-Conway, 2nd Marquess of Hertford | Continued in office |
| Lord Chamberlain of the Household | James Graham, 3rd Duke of Montrose | 14 December 1821 |
| Vice-Chamberlain of the Household | Francis Seymour-Conway, Earl of Yarmouth | Continued in office |
| Vice-Chamberlain of the Household | Robert Jocelyn, Viscount Jocelyn | 28 July 1812 |
| Vice-Chamberlain of the Household | James Graham, Marquess of Graham | 7 February 1821 |
| Master of the Horse | James Graham, 3rd Duke of Montrose | Continued in office |
| Master of the Horse | Charles Sackville-Germain, 5th Duke of Dorset | 12 December 1821 |
| Master of the Buckhounds | Charles Cornwallis, 2nd Marquess Cornwallis | Continued in office |
| Master of the Buckhounds | William Wellesley-Pole, 1st Baron Maryborough | 22 August 1823 |
| Captain of the Gentlemen Pensioners | James Stopford, 3rd Earl of Courtown | Continued in office |
| Captain of the Yeomen of the Guard | George Parker, 4th Earl of Macclesfield | Continued in office |