Liquid dielectric


A liquid dielectric is a dielectric material in liquid state. Its main purpose is to prevent or rapidly quench electric discharges. Dielectric liquids are used as electrical insulators in high voltage applications, e.g. transformers, capacitors, high voltage cables, and switchgear. Its function is to provide electrical insulation, suppress corona and arcing, and to serve as a coolant.
A good liquid dielectric should have high dielectric strength, high thermal stability and inertness against the construction materials used, non-flammability and low toxicity, good heat transfer properties, and low cost.
Liquid dielectrics are self-healing; when an electric breakdown occurs, the discharge channel does not leave a permanent conductive trace in the fluid.
The electrical properties tend to be strongly influenced by dissolved gases, dust, fibers, and especially ionic impurities and moisture. Electrical discharge may cause production of impurities degrading the dielectric's performance.
Some examples of dielectric liquids are transformer oil, perfluoroalkanes, and purified water.
NameDielectric constantMax. breakdown strength Properties
Mineral oil1.0Flammable. Common type of transformer oil.
n-Hexane1.1–1.3Flammable. Used in some capacitors.
n-HeptaneFlammable.
Castor oil natural ester4.7High dielectric constant. Flammable. Refined and dried castor oil is used in some high voltage capacitors.
Hatcol 5005 synthetic ester3.2High dielectric constant. Fire Resistant. Biodegradable PCB replacement. Low temperature fluidity.
Silicone oil2.3–2.8 1.0-1.2More expensive than hydrocarbons. Less flammable.
Fluorinert FC-721.75>0.16More expensive than hydrocarbons. Non flammable and non toxic. High global warming potential. Boiling point of 56°C.
Novec 6491.8>0.16More expensive than hydrocarbons. Non flammable and non toxic. Low global warming potential. Boiling point of 49 °C.
Novec 71007.4>0.01More expensive than hydrocarbons. Higher Dk compared to other perfluoroalkanes. Non flammable and non toxic. Low global warming potential. Boiling point of 61°C.
Polychlorinated biphenylsFormerly used in transformers and capacitors. Persistent organic pollutant, toxic, now phased out. Low flammability.
Purified water78High thermal capacity, good cooling properties. Low electrical conductivity when free of ions.
Benzene2.281.1Toxic, flammable.
Liquid oxygen2.4Cryogenic. Highly flammable with combustible materials.
Liquid nitrogen1.431.6-1.9Cryogenic. Used as coolant with many low-temperature sensors and high-temperature superconductors.
Liquid hydrogen1.0Cryogenic. Flammable.
Liquid helium0.7Cryogenic. Used with superconductors.
Liquid argon1.10–1.42Cryogenic.