Bismuth-209


Bismuth-209 is an isotope of bismuth with the longest known half-life of any nuclide that undergoes α-decay ; the decay product is thallium-205. It has 83 protons and a magic number of 126 neutrons, and naturally-occurring bismuth consists entirely of this isotope.

Decay properties

Bismuth-209 was long thought to have the heaviest stable nucleus of any element, but in 2003, a research team at the in Orsay, France, discovered that Bi undergoes alpha decay with a half-life now given more precisely as years, over 10 times longer than the estimated age of the universe. The heaviest nucleus considered to be stable is now lead-208 and the heaviest stable monoisotopic element is gold.
Theory had previously predicted a half-life of 4.6 years. It had been suspected to be radioactive for a long time. The decay produces a 3.14 MeV alpha particle plus thallium-205.
[Image:Decay Chain(4n+1, Neptunium Series).svg|200px|thumb|right|Bismuth-209 occurs in the neptunium series decay chain.]
Due to its extremely long half-life, Bi can be treated as non-radioactive for nearly all applications. It is much less radioactive than human flesh, so it poses no real radiation hazard. Though Bi holds the half-life record for alpha decay, it does not have the longest known half-life of any nuclide; this distinction belongs to tellurium-128 with a half-life estimated at years by double beta decay.
The half-life of Bi was confirmed in 2012 by an Italian team in Gran Sasso who reported years. They also reported an even longer partial half-life for alpha decay of Bi to the first excited state of Tl, estimated at 1.66 years. Even though this value is shorter than the half-life of Te, both alpha decays of Bi hold the record of the thinnest natural line widths of any measurable physical excitation, estimated respectively at ΔΕ ≈ and ΔΕ ≈ in application of the uncertainty principle.

Applications

Because all primordial bismuth is bismuth-209, bismuth-209 is used for all normal applications of bismuth, such as being used as a replacement for lead, in cosmetics, in paints, and in several medicines such as Pepto-Bismol. Alloys containing bismuth-209 such as bismuth bronze have been used for thousands of years.

Synthesis of other elements

Po can be manufactured by bombarding Bi with neutrons in a nuclear reactor and around 100 grams of Po are produced each year. Po and Po can be made through the proton bombardment of Bi in a cyclotron. Astatine can also be produced by bombarding Bi with alpha particles. Traces of Bi have also been used to create gold in nuclear reactors.
Bi has been used as a target for the creation of several isotopes of superheavy elements such as dubnium, bohrium, meitnerium, roentgenium, and nihonium.

Formation

Primordial

In the red giant stars of the asymptotic giant branch, the s-process is ongoing to produce bismuth-209 and polonium-210 by neutron capture as the heaviest elements to be formed, and the latter quickly decays. All elements heavier than it are formed in the r-process, or rapid process, which occurs during the first fifteen minutes of supernovas. Bismuth-209 is also created during the r-process.

Radiogenic

Some Bi was created radiogenically from the neptunium decay chain. Neptunium-237 is an extinct radionuclide, but it can be found in traces in uranium ores because of neutron capture reactions. This is also ultimately due to the r-process, as every nucleus formed ultimately decayed to bismuth.