Asymmetric Total Synthesis of Pedrolide
Asymmetric Total Synthesis of Pedrolide is a scholarly work, published in 2024 in ''Journal of the American Chemical Society''. The main subjects of the publication include cyclopropanation, stereochemistry, heptane, ring, ring-closing metathesis, olefin metathesis, cyclopentadiene, diterpene, carbene, chemistry, bicyclic compound, Wittig reaction, double displacement reaction, enantioselective synthesis, metathesis, total synthesis, isomerization, stereocenter, and intramolecular force. The asymmetric total synthesis of pedrolide (>200 mg) with an unprecedented 5-5-5-6-6-3 hexacyclic core (pedrolane) was achieved.