Wood drying
Wood drying reduces the moisture content of wood before its use. When the drying is done in a kiln, the product is known as kiln-dried timber or lumber, whereas air drying is the more traditional method.
There are two main reasons for drying wood:
; Woodworking:When wood is used as a construction material, whether as a structural support in a building or in woodworking objects, it will absorb or expel moisture until it is in equilibrium with its surroundings. Equilibration causes unequal shrinkage in the wood, and can cause damage to the wood if equilibration occurs too rapidly. The equilibration must be controlled to prevent damage to the wood.
; Wood burning: When wood is burned, it is usually best to dry it first. Damage from shrinkage is not a problem here, as it may be in the case of drying for woodworking purposes. Moisture affects the burning process, with unburnt hydrocarbons going up the chimney. If a 50% wet log is burnt at high temperature, with good heat extraction from the exhaust gas leading to a 100 °C exhaust temperature, about 5% of the energy of the log is wasted through evaporating and heating the water vapour. With condensers, the efficiency can be further increased; but, for the normal stove, the key to burning wet wood is to burn it very hot, perhaps starting fire with dry wood.
For some purposes, wood is not dried at all, and is used green. Often, wood must be in equilibrium with the air outside, as for construction wood, or the air indoors, as for wooden furniture.
Wood is air-dried or dried in a purpose built oven. Usually the wood is sawn before drying, but sometimes the log is dried whole.
Case hardening describes lumber or timber that has been dried too rapidly. Wood initially dries from the shell, shrinking the shell and putting the core under compression. When this shell has a low moisture content, it will 'set' and resist shrinkage. The core of the wood still has a higher moisture content. This core will then begin to dry and shrink. However, any shrinkage is resisted by the already 'set' shell. This leads to reversed stresses; compression stresses on the shell and tension stresses in the core. This results in unrelieved stress called case hardening. Case-hardened wood may exhibit significant warping when stresses are released by sawing.
Types of wood
Wood is divided, according to its botanical origin, into two kinds: softwoods, from coniferous trees, and hardwoods, from broad-leaved trees. Softwoods are lighter and generally simple in structure, whereas hardwoods are harder and more complex. However, in Australia, softwood generally describes rain forest trees, and hardwood describes Sclerophyll species.Softwoods such as pine are typically much lighter and easier to process than hardwoods such as fruit tree wood. The density of softwoods ranges from to, while hardwoods are to. Once dried, both consist of approximately 12% of moisture. Because of hardwood's denser and more complex structure, its permeability is much less than that of softwood, making it more difficult to dry. Although there are about a hundred times more species of hardwood trees than softwood trees, the ability to be dried and processed faster and more easily makes softwood the main supply of commercial wood nowadays.
Wood–water relationships
The timber of living trees and fresh logs contains a large amount of water which often constitutes over 50% of the wood's weight. Water has a significant influence on wood. Wood continually exchanges moisture or water with its surroundings, although the rate of exchange is strongly affected by the degree to which wood is sealed.Wood contains water in three forms:
; Free water: The bulk of water contained in the cell lumina is only held by capillary forces. It is not bound chemically and is called free water. Free water is not in the same thermodynamic state as liquid water: energy is required to overcome the capillary forces. Furthermore, free water may contain chemicals, altering the drying characteristics of wood.
; Bound or hygroscopic water: Bound water is bound to the wood via hydrogen bonds. The attraction of wood for water arises from the presence of free hydroxyl groups in the cellulose, hemicelluloses and lignin molecules in the cell wall. The hydroxyl groups are negatively charged. Because water is a polar liquid, the free hydroxyl groups in cellulose attract and hold water by hydrogen bonding.
; Vapor: Water in cell lumina in the form of water vapour is normally negligible at normal temperature and humidity.
Moisture content
The moisture content of wood is calculated as the mass change as a proportion of the dry mass, by the formula:Here, is the green mass of the wood, is its oven dry mass. The equation can also be expressed as a fraction of the mass of the water and the mass of the oven dry wood rather than a percentage. For example, expresses the same moisture content as 59%.
Fibre saturation point
When green wood dries, free water from the cell lumina, held by the capillary forces only, is the first to go. Physical properties, such as strength and shrinkage, are generally not affected by the removal of free water. The fibre saturation point is defined as the moisture content at which free water should be completely gone, while the cell walls are saturated with bound water. In most types of woods, the fibre saturation point is at 25 to 30% moisture content. Siau reported that the fibre saturation point is dependent on the temperature T according to the following equation:Keey et al. use a different definition of the fibre saturation point.
Many properties of wood show considerable change as the wood is dried below the fibre saturation point, including:
- volume ;
- strength ;
- electrical resistivity, which increases very rapidly with the loss of bound water when the wood dries below the FSP.
Equilibrium moisture content
The EMC of wood varies with the ambient relative humidity significantly, to a lesser degree with the temperature. Siau reported that the EMC also varies very slightly with species, mechanical stress, drying history of wood, density, extractives content and the direction of sorption in which the moisture change takes place.
Moisture content of wood in service
Wood retains its hygroscopic characteristics after it is put into use. It is then subjected to fluctuating humidity, the dominant factor in determining its EMC. These fluctuations may be more or less cyclical, such as diurnal changes or annual seasonal changes.To minimize the changes in wood moisture content or the movement of wooden objects in service, wood is usually dried to a moisture content that is close to the average EMC conditions to which it will be exposed. These conditions vary for interior uses compared with exterior uses in a given geographic location. For example, according to the Australian Standard for Timber Drying Quality, the EMC is recommended to be 10–12% for the majority of Australian states, although extreme cases are up to 15 to 18% for some places in Queensland, Northern Territory, Western Australia and Tasmania. However, the EMC is as low as 6 to 7% in dry centrally heated houses and offices or in permanently air-conditioned buildings.
Shrinkage and swelling
Shrinkage and swelling may occur in wood when the moisture content is changed. Shrinkage occurs as moisture content decreases, while swelling takes place when it increases. Volume change is not equal in all directions. The greatest dimensional change occurs in a direction tangential to the growth rings. Shrinkage from the pith outwards, or radially, is usually considerably less than tangential shrinkage, while longitudinal shrinkage is so slight as to be usually neglected. The longitudinal shrinkage is 0.1% to 0.3%, in contrast to transverse shrinkages, which is 2% to 10%. Tangential shrinkage is often about twice as great as in the radial direction, although in some species it is as much as five times as great. The shrinkage is about 5% to 10% in the tangential direction and about 2% to 6% in the radial direction.Differential transverse shrinkage of wood is related to:
- the alternation of late wood and early wood increments within the annual ring;
- the influence of wood rays on the radial direction;
- the features of the cell wall structure such as microfibril angle modifications and pits;
- the chemical composition of the middle lamella.
It is probably impossible to completely eliminate dimensional change in wood, but elimination of change in size may be approximated by chemical modification. For example, wood can be treated with chemicals to replace the hydroxyl groups with other hydrophobic functional groups of modifying agents. Among all the existing processes, wood modification with acetic anhydride has been noted for the high anti-shrink or anti-swell efficiency attainable without damage to wood. However, acetylation of wood has been slow to be commercialised due to the cost, corrosion and the entrapment of the acetic acid in wood. There is an extensive volume of literature relating to the chemical modification of wood.
Drying timber is one method of adding value to sawn products from the primary wood processing industries. According to the Australian Forest and Wood Products Research and Development Corporation, green sawn hardwood, which is sold at about $350 per cubic metre or less, increases in value to $2,000 per cubic metre or more with drying and processing. However, currently used conventional drying processes often result in significant quality problems from cracks, both externally and internally, reducing the value of the product. For example, in Queensland, on the assumption that 10% of the dried softwood is devalued by $200 per cubic metre because of drying defects, saw millers are losing about $5 million a year. In Australia, the loss could be $40 million a year for softwood and an equal or higher amount for hardwood. Thus, proper drying under controlled conditions prior to use is of great importance in timber use, in countries where climatic conditions vary considerably at different times of the year.
Drying, if carried out promptly after felling of trees, also protects timber against primary decay, fungal stain and attack by certain kinds of insects. Organisms, which cause decay and stain, generally cannot thrive in timber with a moisture content below 20%. Several, though not all, insect pests can live only in green timber.
In addition to the above advantages of drying timber, the following points are also significant:
- Dried timber is lighter, and the transportation and handling costs are reduced.
- Dried timber is stronger than green timber in most strength properties.
- Timbers for impregnation with preservatives have to be properly dried if proper penetration is to be accomplished, particularly in the case of oil-type preservatives.
- In the field of chemical modification of wood and wood products, the material should be dried to a certain moisture content for the appropriate reactions to occur.
- Dry wood generally works, machines, finishes and glues better than green timber. Paints and finishes last longer on dry timber.
- The electrical and thermal insulation properties of wood are improved by drying.