Trimethylene carbonate

Trimethylene carbonate, or 1,3-propylene carbonate, is a 6-membered cyclic carbonate ester. It is a colourless solid that upon heating or catalytic ring-opening converts to poly(trimethylene carbonate). Such polymers are called aliphatic polycarbonates and are of interest for potential biomedical applications. An isomeric derivative is propylene carbonate, a colourless liquid that does not spontaneously polymerize.

Preparation

This compound may be prepared from 1,3-propanediol and ethyl chloroformate, or from oxetane and carbon dioxide with an appropriate catalyst:
This cyclic carbonate undergoes ring-opening polymerization to give poly, abbreviated PTMC.

Medical devices

The polymer PTC is of commercial interest as a biodegradable polymer with biomedical applications.
A block copolymer of glycolic acid and trimethylene carbonate is the material of the Maxon suture, a monofilament resorbable suture which was introduced in the mid-1980s. The same material is used in other resorbable medical devices.