Cyanuric triazide

Cyanuric triazide is described as an environmentally friendly, low toxicity, and organic primary explosive with a detonation velocity of about 7,300 m s⁻¹ and a autoignition temperature of 205 °C.

Structure

The cyanuric triazide molecule exists as a planar triskelion with molecular point group C_3h. The 1,3,5-triazine ring consists of alternating carbon and nitrogen atoms with C–N bond lengths of 1.334 to 1.336 Å. The distance from the center of the ring to each ring carbon atom is 1.286 Å, while the corresponding distance to ring nitrogens is 1.379 Å. Azide groups are linked to the carbon atoms on the cyanuric ring by single bonds with an interatomic distance of 1.399 Å.

Synthesis

Cyanuric triazide can be synthesized via the nucleophilic aromatic substitution of cyanuric trichloride with an excess of sodium azide in heated acetone. The white crystals can then be purified via recrystallization from −20 °C toluene.
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Decomposition reactions

This white polycrystalline solid was found to be stable under standard conditions but is extremely shock sensitive causing it to violently decompose when ground with a mortar. The thermodynamic properties of cyanuric triazide were studied using bomb calorimetry with a combustion enthalpy of 2234 kJ mol⁻¹ under oxidizing conditions and 740 kJ mol⁻¹ otherwise. The former value is comparable to the military explosive RDX, ₃H₆, but is not put into use due to its less than favorable stability. Melting point examination showed a sharp melting range to clear liquid at 94–95 °C, gas evolution at 155 °C, orange to brown solution discoloration at 170 °C, orange-brown solidification at 200 °C and rapid decomposition at 240 °C. The rapid decomposition at 240 °C results from the formation of elemental carbon as graphite and the formation of nitrogen gas.