Sodium arsenide


Sodium arsenide, also known as trisodium arsenide, is the inorganic compound of sodium and arsenic with the formula. It is a dark colored solid that degrades upon contact with water or air. The compound is mainly of interest as exhibiting an archetypal structure. The normal pressure "sodium arsenide" phase is adopted by many alkali metal pnictides. At, adopts the structure, which is another archetypal structure. Sodium arsenide is a crystalline solid used as a semiconductor and in photo optic applications. Its IUPAC name is disodioarsanylsodium.

Synthesis

It is prepared by passing sodium vapor over preheated elemental arsenic in an evacuated tube and removing excess sodium at under high vacuum.