Pentazolate


In chemistry, a pentazolate is a compound that contains a cyclo-N5 ion, the anion of pentazole. In 2017, researchers prepared the first salt 634Cl containing pentazolate anion starting a substituted phenylpentazole, m-CPBA and iron(II) glycinate. A series of metal and nonmetal pentazolates were subsequently synthesized according to their work.

List of pentazolates

AppearanceDec. temp Ref
LiN5white133
LiN5·3H2Ocolorless139
·2H2Ocolorless111.3
·4H2Ocolorless103.5
Al63·9H2Owhite141.4
·4H2Ocolorless104.1
·4H2Opale green114.7
Fe63·9H2Oreddish brown108.9
·4H2Obright orange58.9
AgN5pale white120
44colorless80
N5white80.8
N5white104.3
N5white88.1
NH4N5white102.0
N2H5N5white85.3
N596.3