Pegmatite
A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than. Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.
Many of the world's largest crystals are found within pegmatites. These include crystals of microcline, quartz, mica, spodumene, beryl, and tourmaline. Some individual crystals are over long.
Most pegmatites are thought to form from the last fluid fraction of a large crystallizing magma body. This residual fluid is highly enriched in volatiles and trace elements, and its very low viscosity allows components to migrate rapidly to join an existing crystal rather than coming together to form new crystals. This allows a few very large crystals to form. While most pegmatites have a simple composition of minerals common in ordinary igneous rock, a few pegmatites have a complex composition, with numerous unusual minerals of rare elements. These complex pegmatites are mined for lithium, beryllium, boron, fluorine, tin, tantalum, niobium, rare earth elements, uranium, and other valuable commodities.
Etymology
The word pegmatite derives from Homeric Greek, πήγνυμι, which means “to bind together”, in reference to the intertwined crystals of quartz and feldspar in the texture known as graphic granite. The term was first used by René Just Haüy in 1822 as a synonym for graphic granite. Wilhelm Karl Ritter von Haidinger first used the term in its present meaning in 1845.General description
Pegmatites are exceptionally coarse-grained igneous rocks composed of interlocking crystals, with individual crystals usually over in size and sometimes exceeding. Most pegmatites have a composition similar to granite, so that their most common minerals are quartz, feldspar, and mica. However, other pegmatite compositions are known, including compositions similar to nepheline syenite or gabbro. The term pegmatite is thus purely a textural description. Geologists typically prefix the term with a compositional description, so that granitic pegmatite is a pegmatite with the composition of granite while nepheline syenite pegmatite is a pegmatite with the composition of nepheline syenite. However, the British Geological Survey discourages this usage, preferring terms like biotite-quartz-feldspar pegmatite for a pegmatite with a typical granitic composition, dominated by feldspar with lesser quartz and biotite. Under BGS terminology, a pegmatitic rock is a coarse-grained rock containing patches of much coarser-grained rock of essentially the same composition.Individual crystals in pegmatites can be enormous in size. It is likely that the largest crystals ever found were feldspar crystals in pegmatites from Karelia with masses of thousands of tons. Quartz crystals with masses measured in thousands of pounds and micas over across and thick have been found. Spodumene crystals over long have been found in the Black Hills of South Dakota, and beryl crystals long and in diameter have been found at Albany, Maine. The largest beryl crystal ever found was from Malakialina on Madagascar, weighing about 380 tons, with a length of and a crosscut of.
Pegmatite bodies are usually of minor size compared to typical intrusive rock bodies. Pegmatite body size is on the order of magnitude of one to a few hundred meters. Compared to typical igneous rocks they are rather inhomogeneous and may show zones with different mineral assemblages. Crystal size and mineral assemblages are usually oriented parallel to the wall rock or even concentric for pegmatite lenses.
Classification
Modern pegmatite classification schemes are strongly influenced by the depth-zone classification of granitic rocks published by Buddington, and the Ginsburg & Rodionov and Ginsburg et al. classification which categorized pegmatites according to their depth of emplacement and relationship to metamorphism and granitic plutons. Cerny’s revision of that classification scheme is widely used, Cerny’s pegmatite classification, which is a combination of emplacement depth, metamorphic grade and minor element content, has provided significant insight into the origin of pegmatitic melts and their relative degrees of fractionation.Granitic pegmatites are commonly ranked into three hierarchies depending upon their mineralogical-geochemical characteristics and depth of emplacement according to Cerny. Classes are Abyssal, Muscovite, Rare-Element and Miarolitic. The Rare-Element Class is subdivided based on composition into LCT and NYF families: LCT for Lithium, Cesium, and Tantalum enrichment and NYF for Niobium, Yttrium, and Fluorine enrichment. Most authors classify pegmatites according to LCT- and NYF-types and subtypes. Another important contribution of the classification is the petrogenetic component of the classification, which shows the association of LCT pegmatites with mainly orogenic plutons, and NYF pegmatites with mainly anorogenic plutons.
Lately, there have been a few attempts to create a new classification for pegmatites less dependent on mineralogy and more reflective of their geological setting. On this issue, one of the most notable efforts on this matter is Wise's pegmatite classification, which focuses mostly on the source of the magma from which the pegmatite crystalizes.
Petrology
Pegmatites form under conditions in which the rate of new crystal nucleation is much slower than the rate of crystal growth. Large crystals are favored. In normal igneous rocks, coarse texture is a result of slow cooling deep underground. It is not clear if pegmatite forms by slow or rapid cooling. In some studies, crystals in pegmatitic conditions have been recorded to grow at a rate ranging from 1 m to 10 m per day.Pegmatites are the last part of a magma body to crystallize. This final fluid fraction is enriched in volatile and trace elements. The residual magma undergoes phase separation into a melt phase and a hydrous fluid phase saturated with silica, alkalis, and other elements. Such phase separation requires formation from a wet magma, rich enough in water to saturate before more than two-thirds of the magma is crystallized. Otherwise, the separation of the fluid phase is difficult to explain. Granite requires a water content of 4 wt% at a pressure of, but only 1.5 wt% at for phase separation to take place.
The volatiles are concentrated in the hydrous phase, greatly lowering its viscosity. The silica in the hydrous phase is completely depolymerized, existing almost entirely as orthosilicate, with all oxygen bridges between silicon ions broken. The low viscosity promotes rapid diffusion through the fluid, allowing growth of large crystals.
When this hydrous fluid is injected into the surrounding country rock, minerals crystallize from the outside in to form a zoned pegmatite, with different minerals predominating in concentric zones. A typical sequence of deposition begins with microcline and quartz, with minor schorl and garnet. This is followed by deposition of albite, lepidolite, gem tourmaline, beryl, spodumene, amblygonite, topaz, apatite, and fluorite, which may partially replace some of the minerals in the earlier zone. The center of the pegmatite may have cavities lined with spectacular gemstone crystals.
Some pegmatites have more complex zoning. Five distinct zones are recognized in the Harding Pegmatite in the Picuris Mountains of northern New Mexico, US. These are:
- A white border rind of fine-grained quartz-albite muscovite pegmatite.
- A continuous layer of very coarse quartz, albite, and muscovite. This zone also contains microcline, and has abundant accessory apatite, beryl, and tantalite. Beryl is occasionally very coarse and abundant.
- A continuous layer of massive quartz. This zone is also rich in muscovite, microcline, and cleavelandite.
- A spectacular quartz and lath-spodumene zone. The spodumene occurs as blade-like crystals, sometimes of enormous size, mostly oriented at random but sometimes arranged to form a comb-like structure. Accessory minerals are beryl, apatite, microcline, and tantalum-niobium minerals, especially in the lower part of this zone. There is some pseudomorphic replacement of spodumene by rose muscovite and quartz by cleavelandite.
- The core of the pegmatite, known as "spotted rock", which is relatively fine-grained spodumene, microcline, and quartz, with accompanying finer-grained albite, lithium-bearing muscovite, lepidolite, microlite, and tantalite. Much of the spodumene and microcline have been extensively corroded and replaced by fine-grained micas.
Because pegmatites likely crystallize from a fluid-dominated phase, rather than a melt phase, they straddle the boundary between hydrothermal mineral deposits and igneous intrusions. Although there is broad agreement on the basic mechanisms by which they form, the details of pegmatite formation remain enigmatic. Pegmatites have characteristics inconsistent with other igneous intrusions. They are not porphyritic, and show no chilled margin. On the contrary, the largest crystals are often found on the margins of the pegmatite body. While aplites are sometimes found on the margins, they are as likely to occur within the body of the pegmatite. The crystals are never aligned in a way that would indicate flow, but are perpendicular to the walls. This implies formation in a static environment. Some pegmatites take the form of isolated pods, with no obvious feeder conduit. As a result, metamorphic or metasomatic origins have sometimes been suggested for pegmatites. A metamorphic pegmatite would be formed by removal of volatiles from metamorphic rocks, particularly felsic gneiss, to liberate the right constituents and water, at the right temperature. A metasomatic pegmatite would be formed by hydrothermal circulation of hot alteration fluids upon a rock mass, with bulk chemical and textural change. Metasomatism is currently not favored as a mechanism for pegmatite formation and it is likely that metamorphism and magmatism are both contributors toward the conditions necessary for pegmatite genesis.