Organoplatinum chemistry
Organoplatinum chemistry is the chemistry of organometallic compounds containing a carbon to platinum chemical bond, and the study of platinum as a catalyst in organic reactions. Organoplatinum compounds exist in oxidation state 0 to IV, with oxidation state II most abundant. The general order in bond strength is Pt-C > Pt-O > Pt-N > Pt-C. Organoplatinum and organopalladium chemistry are similar, but organoplatinum compounds are more stable and therefore less useful as catalysts.
Organoplatinum(0)
Most organoplatinum compounds contain alkene and alkyne ligands. Carbonyl complexes are rare, and the analogue of Ni4 is elusive. The alkene and alkyne ligands serve as two-electron donors, for example in the complexes 2Pt and 2Pt. The ethylene ligand in 2Pt is labile and exchanges with alkynes and electrophilic alkenes, even C60 a fullerene.A general synthetic route to 2Pt is reduction of potassium tetrachloroplatinate with ethanolic potassium hydroxide or hydrazine in presence of a phosphine ligand such as triphenylphosphine and the alkene or alkyne. Such reactions proceed via the intermediacy of cis-dichlorobisplatinum. Nitrogen-based ligands do not often support the formation of platinum complexes of alkenes and alkynes.
Zerovalent organoplatinum complexes lacking phosphine ligands are often prepared via PtCl2.
where C7H10 is norbornene.
Organoplatinum(I)
Platinum compounds are uncommon but generally are diamagnetic because they have Pt-Pt bonds. An example is the dication 2+.Organoplatinum(II)
A historically significant organoplatinum compound is Zeise's salt, which is obtained from ethylene and potassium tetrachloroplatinate:The colourless diolefin complex dichloroplatinum is a more modern relative, and is more widely used.
The stability and diversity of platinum alkene complexes contrasts with the rarity of alkene complexes of nickel. Platinum allyl complexes are also common. In contrast to nickel chemistry, where compounds such as CpNiX are common, cyclopentadienyl derivatives of Pt are rare, consistent with the reluctance of Pt to become pentacoordinate.
Alkyl and aryl platinum complexes are often prepared by oxidative addition of an alkyl halide or aryl halide to a Pt precursor such as tetrakisplatinum or Pt2. Alternatively, platinum chlorides are susceptible to alkylation:
The dimethylsulfide ligands in PtMe22 can be displaced by other ligands.
Many organoplatinum complexes arise via ortho-metalation and related intramolecular C-H activation processes.
Platinum forms certain mono-cyclopentadienide complexes, but platinocene is unstable.
Organoplatinum(IV)
The first organoplatinum compound ever synthesised was trimethylplatinum iodide from platinum chloride and methylmagnesium iodide, reported by Pope and Peachey in 1907. The compound adopts a cubane-like structure with four triply bridging iodide ligands. "Tetramethylplatinum" was claimed in 1952 by Henry Gilman as a derivative of this tetramer, but this claim was later shown to be incorrect. Salts of 2− and 2− have been characterized.File:FUBREA.png|thumb|Structure of 4.
Organoplatinum hydrides are rare. The first isolated representatives were prepared from organotin halides or acids with orthometalated arylplatinum compounds. The compound Me2PtOTf reacts reversibly with triflic acid between -60 and -80 °C, forming methane and 2Pt2 at -20 °C. Weak acids often suffice even water and alcohol and in C-H bond activation the proton source is an alkane.
Catalysis
s based on platinum play a major role in the petrochemical industry, and it is assumed that these useful reactions proceed via surface-bound organoplatinum intermediates. Better defined but less commercially significant are homogeneous catalysts based on platinum.For hydrosilylation, H2PtCl6 is an important catalyst. Mechanisms for this catalytic system usually assume intermediates that contain hydride, silyl ligand, and alkene ligands. Cis-dichlorobisplatinum and Karstedt's catalyst also catalyse hydrosilylation. Many metallodendrimers have repeating units based on organoplatinum compounds.