Neodymium-doped yttrium lithium fluoride
Neodymium-doped yttrium lithium fluoride is a lasing medium for arc lamp-pumped and diode-pumped solid-state lasers. The YLF crystal is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053 nm. It most often appears as a pale pinkish transparent crystal, not unlike rose quartz.
It is used in Q-switched systems in part due
to its relatively long fluorescence lifetime.
As with Nd:YAG lasers, harmonic generation is frequently
employed with Q-switched Nd:YLF
to produce shorter wavelengths. A common application
of frequency-doubled Nd:YLF pulses is to pump ultrafast
Ti:Sapphire chirped-pulse amplifiers.
Neodymium-doped YLF can provide higher pulse energies than Nd:YAG for repetition rates of a few kHz or less. Compared to Nd:YAG, the Nd:YLF crystal is very brittle
and fractures easily. It is also slightly water-soluble — a YLF laser rod may very
slowly dissolve in cooling water which surrounds it.
Physical and chemical properties
Materials: Nd:LiYF4Modulus of Elasticity: 85 GPa
Crystal Structure: Tetragonal
Cell Parameters: a=5.16 Å, c=10.85 Å
Melting Point: 819 °C
Mohs Hardness: 4~5
Density: 3.99 g/cm^3
Thermal Conductivity: 0.063 W/cm/K
Specific Heat: 0.79 J/g/K