Litchfieldite

Litchfieldite is a rare igneous rock. It is a coarse-grained, foliated variety of nepheline syenite, sometimes called nepheline syenite gneiss or gneissic nepeheline syenite. Litchfieldite is composed of two varieties of feldspar, with nepheline, sodalite, cancrinite and calcite. The mafic minerals, when present, are magnetite and an iron-rich variety of biotite.

Occurrence

The rock was named after its occurrence at Litchfield, Maine, USA, by Bayley in 1892.
It is a very rare rock and also occurs in Blue Mountain and French River, Canada; Soroy and Val River, Norway; Cevadais, Portugal; Canaã, Boca Nova, Itajú da Colonia and Peixes, Brazil.

Petrology

Besides the mineral composition litchfieldites are characterized by one or more of the following structures:

A gneissic appearance due to the alternation of leucocratic and mafic bearing mineral bands;
A foliated appearance, due to preferred orientation of platey minerals like lepidomelane biotite,
Parallel orientation of the optical axis of minerals like nepheline.
Occurrence within zoned bodies, enveloped by amphibole bearing syenites and quartz-syenites rocks,
Broken and/or bent twin lamellae in plagioclase,
Mortar structure,
Biotite with kink banding structure and bent cleavage planes,
Occurrence as large boudin or scattered blocks at the surface,
Occurrence within metamorphic belt as elongated bodies parallel to the regional structures,
Isotopic age according to the regional metamorphism

Origin

There are two hypotheses for the origin of these rocks:
Both schools of thought are in accordance that rocks like litchfieldite owe their mineral and structural characteristics to the metamorphism.

Economy

Due to the content of alkali elements and alumina, they are very important ore for the glass industry. The iron-bearing minerals when present are strongly magnetic and can be removed through a magnetic field.

Occurrences of nepheline syenite gneisses in Brazil

Boca Nova

Location: Pará State
Age and determination method
* Country rock last metamorphism age: 900 to 600 my
* Nepheline syenite rocks: 580+/-10 my- K-Ar, biotite; 724 +/- 30 my- Rb-Sr, whole-rock
Rocks and minerals presents
* Alkaline rocks
** nepheline syenite gneiss : nepheline, albite, microcline, perthite, dark green biotite,,,,,,,
** Pegmatites-the same mineralogical composition but poorer in biotite.
* Country rocks: Phyllite, schist with subordinated granite
Metamorphic grade of country rock: High greenschist facies to medium amphibolite facies
Geometry of the alkaline body :Boulders scattered. Geophysical dates suggests elongated bodies parallel to the regional structures.
Textures and structures presents in alkaline rocks: Gneissose appearance; folded foliation; foliation parallel to the country rocks; preferential orientation of biotites parallel to the gneissic band; pegmatites veins with pinch and swell structure parallel and cross cutting the foliation; biotite crystal with kink banding structure; plagioclase with bent twin lamella; feldspar with peristherite; oriented optical axis in nephelines;
Proposed origin: metamorphism of igneous nepheline syenite

Canaã

Localization: Rio de Janeiro State
Age and determination method
* Country rocks last metamorphism age: 900 to 600 my
* Nepheline syenite rocks: 542 +/-14 my Rb-Sr whole rock; 424 +/- 13 my K-Ar in biotite.
Rocks and minerals :
* Alkaline rocks:
**Litchfieldites: Albite, microcline, nepheline, cancrinite, lepidomelane, magnetite,,,,
**Alkali syenite: microcline perthite, quartz, pyroxene, brown biotite,,,,,,,,
**Nepheline bearing pegmatite vein, parallel and cross cutting the foliation of litchfieldite: Feldspar, nepheline,,,,,,.
**Syenite pegmatite: feldspar, corundum, muscovite,,,
* Country rocks: Biotite-sillimanite-gneiss, amphibolites, migmatites,.
Metamorphic grade of country rock: high amphibolite facies
Geometry of the alkaline body: elongated and concordant bodies
Textures and structures presents in alkaline rocks: gneissose appearance, parallel to the country rock foliation; oriented biotite and feldspar; plagioclase with bent twin lamella; kink-banding biotite; oriented optical axis in nephelines; zoned bodies-litchfieldite in center and syenites surrounding.
Proposed origin: metamorphism of igneous nepheline syenite.

Tocantins nepheline syenite gneiss belt

Localization: Tocantins State
Age and determination method:
* Country rocks last metamorphism age: 900 to 600 my
* Nepheline syenite rocks: 1,5 Gy
Rocks and minerals :
* Alkaline rocks:
**Litchfieldite: nepheline, microcline, albite, amphibole, pyroxene,,,,,,.
** Syenite and quartz-syenites:
** Alkaline pegmatites: albite, nepheline, pyroxene, magnetite, zircon,,,,.
* Country rocks: granitic gneisses, amphibolites
Metamorphic grade of country rock: high amphibolite
Geometry of the alkaline body: A belt of elongated zoned bodies parallel to the regional structures.
Textures and structures presents in alkaline rocks: gneissose appearance, foliation, preferred orientation of biotite crystals, faults, boudinage, plagioclase with bent twin lamella; feldspar with peristherite, plagioclase with undulose extinction.
Proposed origin: Metamorphism and metasomatism of igneous nepheline syenite rocks.

Alkaline Rocks Province of South Bahia

Localization: Bahia State
Age and determination method:
* Country rocks last metamorphism age: 900 to 600 my
* Nepheline syenite rocks: 732 +/- 8 my, U-Pb, titanite
Rocks and minerals :
* Alcalines rocks:
**Litchfieldite: albite, microcline, nepheline, dark green biotite, brown biotite,,,,
**Tawite: albite, microcline, sodalite,
**Syenite
**Alkaline pegmatites
* Country rocks: granitic gneiss, migmatite, granulite
Metamorphic grade of country rock: High amphibolite facies
Geometry of the alkaline body: elongated bodies parallel to regional structures.
Textures and structures present in alkaline rocks: elongated and oriented cluster of mafic minerals, plagioclase with bent and broken twin lamella, biotite and muscovite orientation, mortar structures, kink-banding in biotite
Proposed origin: Metamorphic synorogenic alkaline rocks.