Libertyville, IndianaLibertyville is an unincorporated community in Vermillion and Vigo counties, in the U.S. state of Indiana. The county is in the Terre Haute Metropolitan Statistical Area.HistoryA post office was established at Libertyville in 1871, and remained in operation until it was discontinued in 1904.GeographyLibertyville is located along U.S. Highway 150.DemographicsThe United States Census Bureau first delineated Libertyville as a census designated place in the 2022 American Community Survey.