De Wolff graduated from the International School in Jerusalem in the 1960s, which gave him admission to the Mathenesser HBS in Rotterdam where he graduated in 1970. He then studied business sociology and business administration at Erasmus University in Rotterdam where he graduated cum laude in 1976. In 2012 he received his doctorate from the same university with Henri Beunders on a study of subscribers' loyalty to their newspaper.
Career
Leon de Wolff held various journalistic positions at, among others, NRC Handelsblad, Haagse Post and FEM Business. From 1987 he ran his own agency specializing in research, consulting and training. The disease MSA forced him to discontinue much of his work.