Heptasulfur imide


Heptasulfur imide is the inorganic compound with the formula. It is a pale yellow solid that is, like elemental sulfur, highly soluble in carbon disulfide. The compound, which is only of academic interest, is representative of a family of sulfur imides .

Synthesis and structure

It is prepared by reaction of disulfur dichloride with ammonia, although other methods have been developed. Together with, the reaction also produces three isomers of and two isomers of .
Azacyclooctasulfane is an analogue of octasulfur, with one replaced by. The center is almost planar, suggesting that the amine is nonbasic.