Governor Williams
- Abraham J. Williams
- Arnold Williams (American politician)
- Benjamin Williams
- Charles K. Williams
- David Rogerson Williams
- David Williams (Royal Navy officer)
- Fenwick Williams
- G. Mennen Williams
- Jack Williams (American politician)
- James D. Williams
- Jared W. Williams
- John Bell Williams
- Joseph H. Williams
- Martin Williams (diplomat)
- Philip Williams (United States Navy)
- Ralph Champneys Williams
- Ransome Judson Williams
- Robert L. Williams
- Robert Williams (Mississippi politician)
- Roger Williams