Dynamic modulus
Dynamic modulus is the ratio of stress to strain under vibratory conditions. It is a property of viscoelastic materials.
Viscoelastic stress–strain phase-lag
Viscoelasticity is studied using dynamic mechanical analysis where an oscillatory force is applied to a material and the resulting displacement is measured.- In purely elastic materials the stress and strain occur in phase, so that the response of one occurs simultaneously with the other.
- In purely viscous materials, there is a phase difference between stress and strain, where strain lags stress by a 90 degree phase lag.
- Viscoelastic materials exhibit behavior somewhere in between that of purely viscous and purely elastic materials, exhibiting some phase lag in strain.
- Strain:
- Stress:
The stress relaxation modulus is the ratio of the stress remaining at time after a step strain was applied at time :
which is the time-dependent generalization of Hooke's law.
For visco-elastic solids, converges to the equilibrium shear modulus:
The Fourier transform of the shear relaxation modulus is .
Storage and loss modulus
The storage and loss modulus in viscoelastic materials measure the stored energy, representing the elastic portion, and the energy dissipated as heat, representing the viscous portion. The tensile storage and loss moduli are defined as follows:- Storage:
- Loss:
Complex variables can be used to express the moduli and as follows:
where is the imaginary unit.
Ratio between loss and storage modulus
The ratio of the loss modulus to storage modulus in a viscoelastic material is defined as the,, which provides a measure of damping in the material. can also be visualized as the tangent of the phase angle between the storage and loss modulus.Tensile:
Shear:
For a material with a greater than 1, the energy-dissipating, viscous component of the complex modulus prevails.