Densipolic acid
Densipolic acid is a linear fatty acid composed of 18 carbon atoms, with two double bonds in the positions 9=10 and 15=16 and a hydroxyl-OH in the position 12. Although the compound has no nutritional relevance, densipolic acid is an Omega-3 acid.
Discovery
The acid was initially isolated C. R. Smith and colleagues in 1962 from the seed oil of the Lesquerella densipila plant, from which it takes its name.The acid is typically found together with other hydroxylated fatty acids in the seed oil of other Lesquerella species and some Physaria species of the Brassicaceae family.
Chemical properties
The biosynthetic pathways of hydroxylated fatty acids in plants have not been fully researched. There is biochemical evidence that an n-3 desaturase, in acids with 18 carbon atoms a Δ15 desaturase, is able to convert ricinoleic acid to densipolic acid.In seed oils with high concentrations of hydroxylated fatty acids there is the possibility of forming atypical glycerides, such as triglycerides containing more than three acyl groups.