Carbon dichalcogenide


Carbon dichalcogenides are chemical compounds of carbon and chalcogen elements. They have the general chemical formula CZ2, where Z = O, S, Se, Te.
This includes:

Stability

Double bonds between carbon and chalcogen elements, C=Z, become weaker the heavier the chalcogen, Z. This trend means carbon dichalcogenide monomers are less stable and more susceptible to polymerisation as Z changes from O to Te. For example, is stable, polymerises under extreme conditions, tends to polymerise, CSeTe is unstable and does not exist. This trend is an example of the double bond rule.

Bonding

In carbon dichalcogenides, C=O bond lengths are around 1.16 Å, C=S around 1.56 Å, C=Se around 1.70 Å and C=Te around 1.90 Å.
SpeciesFormulaZZ′BondBond in moleculeBond length / ÅMethod of determinationReference
Carbon dioxideCO2OOC=OO=C=O1.163infrared spectroscopy
Carbonyl sulfideOCSOSC=OS=C=O1.158microwave spectroscopy
Carbonyl selenideOCSeOSeC=OSe=C=O1.159microwave spectroscopy
Carbonyl sulfideOCSOSC=SO=C=S1.560microwave spectroscopy
Carbon disulfideSSC=SS=C=S1.553infrared spectroscopy
Thiocarbonyl selenideSCSeSSeC=SSe=C=S1.553microwave spectroscopy
Thiocarbonyl tellurideSCTeSTeC=STe=C=S1.557microwave spectroscopy
Carbonyl selenideOCSeOSeC=SeO=C=Se1.709microwave spectroscopy
Thiocarbonyl selenideSCSeSSeC=SeS=C=Se1.693microwave spectroscopy
Carbon diselenideSeSeC=SeSe=C=Se1.689neutron diffraction
Thiocarbonyl tellurideSCTeSTeC=TeS=C=Te1.904microwave spectroscopy