Bromotoluene

Bromotoluenes are aryl bromides based on toluene in which at least one aromatic hydrogen atom is replaced with a bromine atom. They have the general formula C₇H_8–nBr_n, where n = 1–5 is the number of bromine atoms.

Monobromotoluene

Monobromotoluenes are bromotoluenes containing one bromine atom. There are three isomers, each with the formula C₇H₇Br.

The isomers differ in the location of the bromine, but have the same chemical formula.
Benzyl bromide is an isomer, which has a bromine substituted for one of the hydrogens of toluene's methyl group, and it is sometimes named α-bromotoluene.

A laboratory route to p-bromotoluene proceeds from p-toluidine, which is diazotiized followed by treatment with copper bromide.

Bromotoluenes are precursors to many organic building blocks. For example, the methyl group may be oxidized using potassium permanganate to form the corresponding bromobenzoic acid. The methyl group may also be partially oxidized to form bromobenzaldehyde.