Benzyl potassium


Benzylpotassium is an organopotassium compound with the formula C6H5CH2K, an orange powder. Like organo-alkali metal reagents in general, benzyl potassium is highly reactive, so much so that it reacts with most solvents. It is highly air sensitive.

Synthesis

One early synthesis proceeds by two-step transmetallation reaction by p-tolylpotassium:
A modern synthesis involves the reaction of butyllithium, potassium tert-butoxide, and toluene.
The structure of the related diphenylmethane derivative has been confirmed by X-ray crystallography.