Argentopyrite

Argentopyrite is a moderately rare sulfide mineral with the chemical formula. It is one of the natural compounds of the type, with M being caesium in very rare pautovite, copper in relatively common cubanite, potassium in rare rasvumite and thallium in rare picotpaulite. The type locality is Jáchymov in Czech Republic. Chemically similar mineral include sternbergite, lenaite,, and argentopentlandite,.

Crystal structure

Although previously assumed orthorhombic, argentopyrite was later shown to be monoclinic, with structural relationship to cubanite. The most important feature of the argentopyrite structure are:

hexagonal close-packing of sulfur atoms
presence of and tetrahedra in sheets displaying corner-sharing
presence of a cluster of four tetrahedra that share edges
presence of two iron sites, instead of one as in related species
ordered-disordered ferrous-ferric nature of the mineral