Anti-structure


In crystallography, an anti-structure is obtained from a salt structure by exchanging anion and cation positions.
For instance, calcium fluoride, CaF2, crystallizes in a cubic motif called the fluorite structure. The same crystal structure is found in numerous ionic compounds with formula AB2, such as ceria, zirconia, uranium dioxide. In the corresponding anti-structure, called the antifluorite structure, anions and cations are swapped, such as beryllium carbide or lithium oxide, potassium sulfate.
Other anti-structures include:
  • anti-SnO2: Ti2N
  • anti-PbCl2: Co2P
  • anti-CdCl2: Co2N
  • anti-CdI2: Cs2O
  • anti-NbS2: Hf2S
  • anti-ReO3: Cu3N
  • anti-LaF3: Cu3P, Cu3As