| 1 | nowrap|1981–1998
Others- Most career league appearances: 622, Andoni Zubizarreta and Joaquín
- Most career league appearances at one club: 550, Raúl
- Most career league appearances by a foreign player: 529, Antoine Griezmann
- Most consecutive league appearances: 251, Iñaki Williams
- Oldest player: Joaquín, 41 years, 318 days
- Oldest player under exceptional circumstances: Harry Lowe, 48 years, 226 days
- Youngest player: Luka Romero, 15 years, 219 days
- Most appearances with different teams: 8
- * Sandro Ramírez
- * Carlos Aranda
GoalscorersTop goalscorersPlayers in bold are still active in La Liga. Players in italics are still active outside La Liga.
| Rank | Nat. | Player | Years active | Goals | Apps | Ratio | | 1 | #expr:472/518 round 2
Most goals in a La Liga season (at least 35 goals)Bold player name denotes current season.
| Rank | Nat. | Player | Season | Club | Goals | Apps | Ratio | | 1 | #expr:50/37 round 3
Most hat-tricks in the League (at least 10)Three or more goals in a single match. For the complete list of hat-tricks see List of La Liga hat-tricks. Players in bold are still active in La Liga. Players in italics are still active outside La Liga. Players with at least 10 hat-tricks are shown in this table.
| Rank | Player | Hat-tricks | Last hat-trick | | 1 | 
Fastest goalsYoungest and oldest- Oldest goalscorer: 40 years and 138 days, Donato
- Youngest goalscorer: 16 years and 87 days, Lamine Yamal
Others- Most career league goals: 474, Lionel Messi
- Most goals scored in a season: 50, Lionel Messi
- Most league goals scored in a calendar year: 59, Lionel Messi
- Most league home goals in a season : 35, Lionel Messi
- Most league away goals in a season : 24, Lionel Messi
- Most career La Liga matches scored in: 300, Lionel Messi
- Most league matches scored in a season : 27, Lionel Messi
- Most league home matches scored in a season : 16, Lionel Messi
- Most league away matches scored in a season : 15, Lionel Messi
- Most opponents scored against in La Liga history: 38, Lionel Messi
- Most opponents scored against in a season: 19, joint record:
- *Ronaldo for Barcelona
- *Cristiano Ronaldo for Real Madrid
- *Lionel Messi for Barcelona
- Most consecutive hat-tricks in one season: 3, Isidro Lángara
- Most goals scored in a game: 7, joint record:
- * Agustín Sauto Arana
- * László Kubala
- Most goals scored in different seasons: 19, Agustín Gaínza
- Most consecutive league appearances scored in: 21, Lionel Messi
- Most consecutive home league matches scored in: 18, Mariano Martín
- Most consecutive away league matches scored in: 13, Lionel Messi
- Most hat-tricks scored in La Liga history: 36, Lionel Messi
- Most league hat-tricks scored in a season: 8, joint record:
- * Lionel Messi
- * Cristiano Ronaldo
- Most braces scored in La Liga history: 133, Lionel Messi
- Fastest hat-trick in La Liga: 3 minutes and 57 seconds, Alexander Sørloth
- Oldest player to score a hat-trick in La Liga: 39 years and 241 days, Jorge Molina
- Youngest player to score a hat-trick in La Liga: 17 years and 337 days, José Iraragorri
- Most goals scored from direct free kicks: 39, Lionel Messi
- Most goals from penalties in La Liga history: 61, Cristiano Ronaldo
- Most penalties taken in La Liga history: 73, Lionel Messi
- Most goals scored with different teams: 7
- * Miquel Soler
- * Carlos Aranda
- * Roberto Soldado
- * Munir El Haddadi
- Only player to score 30+ goals in 8 different seasons: Lionel Messi
- Only player to score 4 goals in 2 consecutive matches in La Liga history in a single season: 2, Luis Suárez
- Only players to be involved in 7 goals in a single match in La Liga history: joint record:
- *Agustín Sauto Arana
- *László Kubala
- *Luis Suárez,
- Most opening goals in La Liga history: 103, Lionel Messi
- Most stadiums scored at in La Liga history: 37, Lionel Messi
- Most goals scored as a substitute: 35, Cristhian Stuani
- Most goals scored as a substitute in a season: 12, Alexander Sørloth
- Most goals scored by a goalkeeper: 6, joint record:
- * Carlos Fenoy
- * Nacho González
- Most goals scored by a goalkeeper in a season: 5, Carlos Fenoy
- Most goals scored by a goalkeeper in a game: 2, Nacho González
GoalkeepingLongest goalkeeping runs without conceding a goal| Rank | Nat. | Player | Season | Club | Minutes | | 1 | 
Others- Most saves in a single season: 162, Guillermo Ochoa
- Most clean sheets: 233, Andoni Zubizarreta
- Most clean sheets in a season: 26, joint record:
- *Francisco Liaño
- *Marc-André ter Stegen
- Best conceded goal quota in a season :
- *1 – 0.474 goals per game, Francisco Liaño, Jan Oblak, Marc-André ter Stegen
- *4 – 0.5 goals per game, Víctor Valdés
- Longest start to a season with no goals conceded: 754 minutes, Claudio Bravo
- Longest goalkeeping run without conceding a goal: 1,275 minutes, Abel Resino
- Most penalties saved: 22, Diego Alves for Almería and Valencia
- Most penalties saved in a single season: 6, Diego Alves for Valencia, 2016–17
AssistsWinsDisciplinaryManagersMost matches managedCoaches in bold are still active in La Liga.
| Rank | Nat. | Coach | Years | Matches | | 1 | nowrap|1974–2004
Most matches wonCoaches in bold are still active in La Liga.
| Rank | Nat. | Coach | Years | Matches | Wins | | 1 | nowrap|1974–2004
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