Margarine


Margarine is a spread used for flavoring, baking, and cooking. It is most often used as a substitute for butter. Although originally made from animal fats, most margarine consumed today is made from vegetable oil. The spread was originally named oleomargarine from Latin for oleum and Greek margarite. The name was later shortened to margarine, or sometimes oleo.
Margarine consists of a water-in-fat emulsion, with tiny droplets of water dispersed uniformly throughout a fat phase in a stable solid form. While butter is made by concentrating the butterfat of milk through centrifugation, modern margarine is made through a more intensive processing of refined vegetable oil and water.
Per US federal regulation, products must have a minimum fat content of 80% to be labeled "margarine" in the United States, although the term is used informally to describe vegetable-oil-based spreads with lower fat content.
Margarine can be used as an ingredient in other food products, such as pastries, doughnuts, cakes, and cookies.

History

Invention and early distribution

Margarine has its roots in the discovery by French chemist Michel Eugène Chevreul in 1813 of margaric acid. Scientists at the time regarded margaric acid, like oleic acid and stearic acid, as one of the three fatty acids that, in combination, form most animal fats. In 1853, the German structural chemist Wilhelm Heinrich Heintz analyzed margaric acid as simply a combination of stearic acid and the previously unknown palmitic acid.
After the French Emperor Napoleon III issued a challenge to create a butter-substitute from beef tallow for the armed forces and lower classes, Hippolyte Mège-Mouriès invented margarine in 1869. Mège-Mouriès patented the product, which he named "oleomargarine", and expanded his initial manufacturing operation from France, but had little commercial success. In 1871, he sold the patent to the Dutch company Jurgens, which subsequently became part of Unilever. In the same year a German pharmacist, Benedict Klein from Cologne, founded the first margarine factory in Germany, producing the brands Overstolz and Botteram.
The principal raw material in the original formulation of margarine was beef fat. In 1871, Henry W. Bradley of Binghamton, New York, received US Patent 110626 for a process of creating margarine that combined vegetable oils with animal fats. In 1874, the first commercial cargo arrived in the UK. By the late-19th century, some 37 companies were manufacturing margarine in the US, in opposition to the butter industry, which protested and lobbied for government intervention, eventually leading to the 1886 Margarine Act imposing prohibitive taxes and fees against margarine manufacturers.
Shortages in beef fat supply, combined with advances by James F. Boyce and Paul Sabatier in the hydrogenation of plant materials, soon accelerated the use of Bradley's method, and between 1900 and 1920, commercial oleomargarine was produced from a combination of animal fats and hardened and unhardened vegetable oils. The Great Depression, followed by rationing in the United States and in the United Kingdom, among other countries, during World War II, led to a reduction in supply of animal fat and butter, and, by 1945, "original" margarine had almost completely disappeared from the market. In the United States, problems with supply, coupled with changes in legislation, caused margarine manufacturers to switch almost completely to vegetable oils and fats by 1950; thus the margarine industry was ready for an era of product development.

Color debate

in the milk of grass-fed cows gives butter produced from such milk a slightly yellow color. However, being a synthetic product, margarine has a white color resembling lard, which many people found unappetizing. Around the late 1880s, manufacturers began coloring margarine yellow to improve sales.
Dairy firms, especially in Wisconsin, became alarmed at the potential threat to their business, and succeeded in getting legislation passed to prohibit the coloring of the stark white margarine by 1902. In response, margarine companies distributed margarine together with a packet of yellow food coloring. The product was placed in a bowl and the coloring mixed in manually, taking some time and effort, especially if the mixing needed to be done by hand—typically the case at the time since domestic electric mixers were rarely used before the 1920s. It was therefore not unusual for the final product to be served as a light and dark yellow, or even white, striped product. During World War II, butter and margarine were both in short supply and subject to rationing in the United States, but butter required more points, causing margarine to gain popularity. In 1951, the W. E. Dennison Company received US Patent 2553513 for a method to place a capsule of yellow dye inside a plastic package of margarine. After purchase, the capsule was broken by pressing on the outside of the package, and the package was kneaded to distribute the dye.
The artificial coloring laws began being repealed around 1955, and margarine could once again be sold colored like butter in most states. The final hold out was Wisconsin, which finally repealed its restrictions in 1967.

Coal butter

Around the 1930s and 1940s, Arthur Imhausen developed and implemented an industrial process in Germany for producing edible fats by oxidizing synthetic paraffin wax made from coal. The products were fractionally distilled and the edible fats were obtained from the – fraction which were reacted with glycerol such as that synthesized from propylene. Margarine made from them was found to be nutritious and of agreeable taste, and it was incorporated into diets contributing as much as 700 calories per day. The process required at least 60 kilograms of coal per kilogram of synthetic butter. That industrial process was discontinued after WWII due to its inefficiency.

Post-WWII

During the Second World War and immediate post-war years amid rationing in the United Kingdom, only two types of margarine were available: a premium brand and a budget brand with whale oil being used in its manufacture. With the end of rationing in 1955, the market was opened to the forces of supply and demand, and brand marketing became prevalent. The competition among the major producers was given further impetus with the beginning of commercial television advertising in 1955 and, throughout the 1950s and 1960s, competing companies vied to produce the margarine that tasted most like butter.

Spread products

In the mid-1960s, the introduction of two lower-fat blends of butter oil and vegetable oils in Scandinavia, called Lätt & Lagom and Bregott, clouded the issue of what should be called "margarine" and began the debate that led to the introduction of the term "spread". In 1978, an 80% fat product called Krona, made by churning a blend of dairy cream and vegetable oils, was introduced in Europe and, in 1982, a blend of cream and vegetable oils called Clover was introduced in the UK by the Milk Marketing Board. The vegetable oil and cream spread I Can't Believe It's Not Butter! was introduced into the United States in 1981, and in the United Kingdom and Canada in 1991. In the US, products with less than 80% fat can be labeled spreads, but they can not be called margarine. Since the word margarine is less popular with consumers, manufacturers developed some products to have slightly less than the minimum amount of fat, so that they can legally avoid labeling their products as margarine.
In the 21st century, margarine spreads had many developments to improve their consumer appeal. Most brands phased out the use of hydrogenated oils and became trans fat free. Many brands launched refrigerator-stable margarine spreads that contain only one-third of the fat and calorie content of traditional spreads. Other varieties of spreads include those with added omega-3 fatty acids, low or no salt, added plant sterols, olive oil, or certified vegan oils. In the early 21st century, manufacturers provided margarines in plastic squeeze bottles to ease dispensing and offered pink margarine as a novelty.

Manufacturing process

The basic method of making margarine today consists of emulsifying a blend of oils and fats from vegetable and animal sources, which can be modified using fractionation, interesterification or hydrogenation, with skimmed milk which may be fermented or soured, salt, citric or lactic acid, chilling the mixture to solidify it, and working it to improve the texture. Margarines and vegetable fat spreads found in the market can range from 10% to 90% fat, depending on dietary marketing and purpose. The softer tub margarines are made with less hydrogenated and more liquid oils than block margarines.
Three types of margarine are common:
  • Bottled liquid margarine to cook or top dishes.
  • Soft vegetable fat spreads, high in mono- or polyunsaturated fats, which are made from safflower, sunflower, soybean, cottonseed, rapeseed, or olive oil.
  • Hard margarine for cooking or baking.
To produce margarine, first oils and fats are extracted, e.g. by pressing from seeds, and then refined. Oils may undergo a full or partial hydrogenation process to solidify them. The milk/water mixture is kept separate from the oil mixture until the emulsion step. The fats are warmed so that they are liquid during the mixing process. The water-soluble additives are added to the water or milk mixture, and emulsifiers such as lecithin are added to help disperse the water phase evenly throughout the oil. Other water-soluble additives include powdered skim milk, salt, citric acid, lactic acid, and preservatives such as potassium sorbate. The fat soluble additives are mixed into the oil. These include carotenoids for coloring and antioxidants. Then the two mixtures are emulsified by slowly adding the oil into the milk/water mixture with constant stirring. Next, the mixture is cooled. Rapid chilling avoids the production of large crystals and results in a smooth texture. The product is then rolled or kneaded. Finally, the product may be aerated with nitrogen to facilitate spreading it.