Lead(II) nitrate
Lead nitrate is an inorganic compound with the chemical formula. It commonly occurs as a colourless crystal or white powder and, unlike most other lead salts, is soluble in water.
Known since the Middle Ages by the name plumbum dulce, the production of lead nitrate from either metallic lead or lead oxide in nitric acid was small-scale, for direct use in making other lead compounds. In the nineteenth century lead nitrate began to be produced commercially in Europe and the United States. Historically, the main use was as a raw material in the production of pigments for lead paints, but such paints have been superseded by less toxic paints based on titanium dioxide. Other industrial uses included heat stabilization in nylon and polyesters, and in coatings of photothermographic paper. Since around the year 2000, lead nitrate has begun to be used in gold cyanidation.
Lead nitrate is toxic and must be handled with care to prevent inhalation, ingestion and skin contact. Due to its hazardous nature, the limited applications of lead nitrate are under constant scrutiny.
History
Lead nitrate was first identified in 1597 by the alchemist Andreas Libavius, who called the substance plumbum dulce, meaning "sweet lead", because of its taste. It is produced commercially by reaction of metallic lead with concentrated nitric acid in which it is sparingly soluble. It has been produced as a raw material for making pigments such as chrome yellow and chrome orange and Naples yellow ). These pigments were used for dyeing and printing calico and other textiles. It has been used as an oxidizer in black powder and together with lead azide in special explosives.Production
Lead nitrate is produced by reaction of lead oxide with concentrated nitric acid:It may also be obtained by evaporation of the solution obtained by reacting metallic lead with dilute nitric acid.
Solutions and crystals of lead nitrate are formed in the processing of lead–bismuth wastes from lead refineries.
Structure
The crystal structure of solid lead nitrate has been determined by neutron diffraction. The compound crystallizes in the cubic system with the lead atoms in a face-centred cubic system. Its space group is Pa3, with each side of the cube with length.The black dots represent the lead atoms, the white dots the nitrate groups above the plane of the lead atoms, and the blue dots the nitrate groups the same distance below this plane. In this configuration, every lead atom is bonded to twelve oxygen atoms. All bond lengths are identical, at.
Research interest in the crystal structure of lead nitrate was partly based on the possibility of free internal rotation of the nitrate groups within the crystal lattice at elevated temperatures, but this did not materialise.
Chemical properties and reactions
Lead nitrate is an oxidizer and has been used as such in pyrotechnics.Basic nitrates are formed when alkali is added to a solution. is the predominant species formed at low pH. At higher pH is formed. The cation is unusual in having an oxide ion inside a cluster of 3 face-sharing tetrahedra.
There is no evidence for the formation of the hydroxide,, in aqueous solution below pH 12.
Solutions of lead nitrate can be used to form co-ordination complexes. Lead is a hard acceptor; it forms stronger complexes with nitrogen and oxygen electron-donating ligands. For example, combining lead nitrate and pentaethylene glycol in a solution of acetonitrile and methanol followed by slow evaporation produced the compound . In the crystal structure for this compound, the EO5 chain is wrapped around the lead ion in an equatorial plane similar to that of a crown ether. The two bidentate nitrate ligands are in trans configuration. The total coordination number is 10, with the lead ion in a bicapped square antiprism molecular geometry.
The complex formed by lead nitrate with a bithiazole bidentate N-donor ligand is binuclear. The crystal structure shows that the nitrate group forms a bridge between two lead atoms. One aspect of this type of complex is the presence of a physical gap in the coordination sphere; i.e., the ligands are not placed symmetrically around the metal ion. This is potentially due to a lone pair of lead electrons, also found in lead complexes with an imidazole ligand.
Applications
Lead nitrate has been used as a heat stabiliser in nylon and polyesters, as a coating for photothermographic paper, and in rodenticides.Heating lead nitrate is convenient means of making nitrogen dioxide:
In the gold cyanidation process, addition of lead nitrate solution improves the leaching process. Only limited amounts are required.
In organic chemistry, it may be used in the preparation of isothiocyanates from dithiocarbamates. Its use as a bromide scavenger during S1 substitution has been reported.