Tetraethyl orthosilicate
Tetraethyl orthosilicate, formally named tetraethoxysilane or ethyl silicate is an organic compound with the formula. TEOS is a colorless liquid. It degrades in water. TEOS is the ethyl ester of orthosilicic acid,. It is the most prevalent alkoxide of silicon.
TEOS is a tetrahedral molecule at Si atom. Like its many analogues, it is prepared by alcoholysis of silicon tetrachloride:
Applications
TEOS is mainly used as a crosslinking agent in silicone polymers and as a precursor to silicon dioxide in the semiconductor industry.TEOS is also used as the silica source for synthesis of some zeolites. Other applications include coatings for carpets and other objects. TEOS is used in the production of aerogel. These applications exploit the reactivity of the Si-OR bonds. TEOS has historically been used as an additive to alcohol based rocket fuels to decrease the heat flux to the chamber wall of regeneratively cooled engines by over 50%.
TEOS is used in steel casting industry as an inorganic binder and stiffener for making silica-based ceramic molding forms. and as an inorganic binder for coatings of different materials such as steel, glass, brass, and wood in order to make surfaces resistant to water, oxygen and high temperatures.. Further applications of TEOS include its use as an additive to solid polymers to enhance their adhesion to glass, steel or wood, as a binder for porcelain teeth crowns, and as a precursor to siloxanes.
Other reactions
TEOS easily converts to silicon dioxide upon the addition of water:An idealized equation is shown, in reality the silica produced is hydrated. This hydrolysis reaction is an example of a sol-gel process. The side product is ethanol. The reaction proceeds via a series of condensation reactions that convert the TEOS molecule into a mineral-like solid via the formation of Si-O-Si linkages. Rates of this conversion are sensitive to the presence of acids and bases, both of which serve as catalysts. The Stöber process allows the formation of monodisperse and mesoporous silica.
At elevated temperatures, TEOS converts to silicon dioxide:
The volatile coproduct is diethyl ether.