Carnauba wax
Carnauba, also called Brazil wax and palm wax, is a wax of the leaves of the carnauba palm Copernicia prunifera, a plant native to and grown only in the northeastern Brazilian states of Ceará, Piauí, Paraíba, Pernambuco, Rio Grande do Norte, Maranhão and Bahia. It is known as the "Queen of Waxes". In its pure state, it is usually available in the form of hard yellow-brown flakes. It is obtained by collecting and drying the leaves, beating them to loosen the wax, then refining and bleaching it.
As a food additive, its E number is E903.
Composition
Carnauba consists mostly of aliphatic esters, diesters of 4-hydroxycinnamic acid, ω-hydroxycarboxylic acids, and fatty alcohols. The compounds are predominantly derived from acids and alcohols in the C26-C30 range. It is distinctive for its high content of diesters and its methoxycinnamic acid.It is sold in grades of T1, T3 and T4 according to its purity level, which is accomplished by filtration, centrifugation and bleaching.
Properties
As it creates a glossy finish, carnauba wax is used in automobile waxes, shoe polishes, dental floss, food products, polishes for musical instruments, and floor and furniture waxes and polishes. It is commonly used for paper coatings in the United States.It is also used to make cutler's resin for attaching handles to bladed tools and weapons.
Although too brittle to be used alone, carnauba wax is often combined with other waxes to treat and waterproof leather products, where it provides a high-gloss finish and increases leather's hardness and durability.
In 1890, carnauba wax was patented as a replacement for the standard paraffin/beeswax mixture used in phonograph cylinders.
Carnauba wax may be used as a mold release agent for manufacturing fibre-reinforced plastics. An aerosol form is made by dissolving it in a solvent. Unlike silicone or PTFE, carnauba is suitable for use with liquid epoxy, epoxy molding compounds, and some other plastic types. It is not very soluble in chlorinated or aromatic hydrocarbons.
It is used in melt/castable explosives to produce an insensitive explosive formula such as Composition B, which is a blend of RDX and TNT.
Production and export
In 2006, Brazil produced 22,409 tons of carnauba wax, of which 14% was solid and 86% was in powder form.There are 20 to 25 exporters of carnauba wax in Brazil who, after buying it from middlemen or directly from farmers, refine the wax before shipping it to the rest of the world.
The four largest exporters are Pontes, Brasil Ceras, Foncepi, and Carnauba do Brasil, who together account for around €25 million of the export market. According to the German television program , conditions for many carnauba production workers are quite poor; one Brazilian Labor Ministry official found conditions "that could be described as slavery."
According to the Brazilian Ministry of Development, Industry and Foreign Trade, the major destinations for exported carnauba wax are:
- United States
- Japan
- Germany
- Netherlands
- Italy
- China
- Other countries
Technical characteristics
- INCI name: Copernicia cerifera wax
- Melting point:
- Relative density: ~0.97
- Among the hardest of natural waxes
- Practically insoluble in water or ethyl alcohol
- Soluble by heating in ethyl acetate or xylene