List of copper alloys
Copper alloys are metal alloys that have copper as their principal component. They have high resistance against corrosion. Of the large number of different types, the best known traditional types are bronze, where tin is a significant addition, and brass, using zinc instead. Both of these are imprecise terms. Latten is a further term, mostly used for coins with a very high copper content. Today the term "copper alloy" tends to be substituted for all of these, especially by museums.
Copper deposits are abundant in most parts of the world, and it has therefore always been a relatively cheap metal. By contrast, tin is relatively rare, and in Europe and the Mediterranean region, even in prehistoric times, it had to be traded considerable distances and was expensive, sometimes virtually unobtainable. Zinc is even more common at 75 parts per million but is harder to extract from its ores. Bronze with the ideal percentage of tin was therefore expensive, and the proportion of tin was often reduced to save cost. The discovery and exploitation of the Bolivian tin belt in the 19th century made tin far cheaper, although forecasts for future supplies are less positive.
There are as many as 400 different copper and copper alloy compositions loosely grouped into the categories: copper, high copper alloy, brasses, bronzes, cupronickel, copper-nickel-zinc, leaded copper, and special alloys.
Composition
The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the Bronze Age, are vaguer, as the mixtures were generally variable.| Family | Principal alloying element | UNS numbers |
| Copper alloys, brass | Zinc | C1xxxx-C4xxxx,C66400-C69800 |
| Phosphor bronze | Tin | C5xxxx |
| Aluminium bronzes | Aluminium | C60600-C64200 |
| Silicon bronzes | Silicon | C64700-C66100 |
| Cupronickel, nickel silvers | Nickel | C7xxxx |
| Name | Nominal composition | Form and condition | Yield strength | Tensile strength | Elongation in 2 inches | Hardness | Comments |
| Copper | Cu 99.9 | Annealed | 10 | 32 | 45 | 42 | Electrical equipment, roofing, screens |
| Copper | Cu 99.9 | Cold-drawn | 40 | 45 | 15 | 90 | Electrical equipment, roofing, screens |
| Copper | Cu 99.9 | Cold-rolled | 40 | 46 | 5 | 100 | Electrical equipment, roofing, screens |
| Gilding metal | Cu 95.0, Zn 5.0 | Cold-rolled | 50 | 56 | 5 | 114 | Coins, bullet jackets |
| Cartridge brass | Cu 70.0, Zn 30.0 | Cold-rolled | 63 | 76 | 8 | 155 | Good for cold-working; radiators, hardware, electrical, drawn cartridge cases. |
| Phosphor bronze | Cu 89.75, Sn 10.0, P 0.25 | Spring temper | — | 122 | 4 | 241 | High fatigue-strength and spring qualities |
| Yellow or High brass | Cu 65.0, Zn 35.0 | Annealed | 18 | 48 | 60 | 55 | Good corrosion resistance |
| Yellow or High brass | Cu 65.0, Zn 35.0 | Cold-drawn | 55 | 70 | 15 | 115 | Good corrosion resistance |
| Yellow or High brass | Cu 65.0, Zn 35.0 | Cold-rolled | 60 | 74 | 10 | 180 | Good corrosion resistance |
| Manganese bronze | Cu 58.5, Zn 39.2, Fe 1.0, Sn 1.0, Mn 0.3 | Annealed | 30 | 60 | 30 | 95 | Forgings |
| Manganese bronze | Cu 58.5, Zn 39.2, Fe 1.0, Sn 1.0, Mn 0.3 | Cold-drawn | 50 | 80 | 20 | 180 | Forgings |
| Naval brass | Cu 60.0, Zn 39.25, Sn 0.75 | Annealed | 22 | 56 | 40 | 90 | Resistance to salt corrosion |
| Naval brass | Cu 60.0, Zn 39.25, Sn 0.75 | Cold-drawn | 40 | 65 | 35 | 150 | Resistance to salt corrosion |
| Muntz metal | Cu 60.0, Zn 40.0 | Annealed | 20 | 54 | 45 | 80 | Condenser tubes |
| Aluminium bronze | Cu 92.0, Al 8.0 | Annealed | 25 | 70 | 60 | 80 | — |
| Aluminium bronze | Cu 92.0, Al 8.0 | Hard | 65 | 105 | 7 | 210 | — |
| Beryllium copper | Cu 97.75, Be 2.0, Co or Ni 0.25 | Annealed, solution-treated | 32 | 70 | 45 | B60 | Electrical, valves, pumps, oilfield tools, aerospace landing gears, robotic welding, mold making |
| Beryllium copper | Cu 97.75, Be 2.0, Co or Ni 0.25 | Cold-rolled | 104 | 110 | 5 | B81 | Electrical, valves, pumps, oilfield tools, aerospace landing gears, robotic welding, mold making |
| Free-cutting brass | Cu 62.0, Zn 35.5, Pb 2.5 | Cold-drawn | 44 | 70 | 18 | B80 | Screws, nuts, gears, keys |
| Nickel silver | Cu 65.0, Zn 17.0, Ni 18.0 | Annealed | 25 | 58 | 40 | 70 | Hardware |
| Nickel silver | Cu 65.0, Zn 17.0, Ni 18.0 | Cold-rolled | 70 | 85 | 4 | 170 | Hardware |
| Nickel silver | Cu 76.5, Ni 12.5, Pb 9.0, Sn 2.0 | Cast | 18 | 35 | 15 | 55 | Easy to machine; ornaments, plumbing |
| Cupronickel | Cu 88.35, Ni 10.0, Fe 1.25, Mn 0.4 | Annealed | 22 | 44 | 45 | – | Condenser, salt-water pipes |
| Cupronickel | Cu 88.35, Ni 10.0, Fe 1.25, Mn 0.4 | Cold-drawn tube | 57 | 60 | 15 | – | Condenser, salt-water pipes |
| Cupronickel | Cu 70.0, Ni 30.0 | Wrought | – | – | – | – | Heat-exchange equipment, valves |
| Ounce metal Copper alloy C83600 | Cu 85.0, Zn 5.0, Pb 5.0, Sn 5.0 | Cast | 17 | 37 | 25 | 60 | — |
| Gunmetal | Varies Cu 80-90%, Zn <5%, Sn ~10%, +other elements@ <1% | - |
| Family | CDA | ASTM | SAE | SAE superseded | Federal | Military |
| Red brass | 833 | |||||
| Red brass | 836 | B145-836 | 836 | 40 | QQ-C-390 | C-2229 Gr2 |
| Red brass | 838 | B145-838 | 838 | QQ-C-390 | ||
| Semi-red brass | 844 | B145-844 | QQ-C-390 | |||
| Semi-red brass | 848 | B145-848 | QQ-C-390 | |||
| Manganese bronze | 862 | B147-862 | 862 | 430A | QQ-C-390 | C-2229 Gr9 |
| Manganese bronze | 863 | B147-863 | 863 | 430B | QQ-C-390 | C-2229 Gr8 |
| Manganese bronze | 865 | B147-865 | 865 | 43 | QQ-C-390 | C-2229 Gr7 |
| Tin bronze | 903 | B143-903 | 903 | 620 | QQ-C-390 | C-2229 Gr1 |
| Tin bronze | 905 | B143-905 | 905 | 62 | QQ-C-390 | |
| Tin bronze | 907 | 907 | 65 | |||
| Leaded tin bronze | 922 | B143-922 | 922 | 622 | QQ-C-390 | B-16541 |
| Leaded tin bronze | 923 | B143-923 | 923 | 621 | QQ-C-390 | C-15345 Gr10 |
| Leaded tin bronze | 926 | 926 | ||||
| Leaded tin bronze | 927 | 927 | 63 | |||
| High-leaded tin bronze | 932 | B144-932 | 932 | 660 | QQ-C-390 | C-15345 Gr12 |
| High-leaded tin bronze | 934 | QQ-C-390 | C-22229 Gr3 | |||
| High-leaded tin bronze | 935 | B144-935 | 935 | 66 | QQ-C-390 | |
| High-leaded tin bronze | 937 | B144-937 | 937 | 64 | QQ-C-390 | |
| High-leaded tin bronze | 938 | B144-938 | 938 | 67 | QQ-C-390 | |
| High-leaded tin bronze | 943 | B144-943 | 943 | QQ-C-390 | ||
| Aluminium bronze | 952 | B148-952 | 952 | 68A | QQ-C-390 | C-22229 Gr5 |
| Aluminium bronze | 953 | B148-953 | 953 | 68B | QQ-C-390 | |
| Aluminium bronze | 954 | B148-954 | 954 | QQ-C-390 | C-15345 Gr13 | |
| Aluminium bronze | 955 | B148-955 | 955 | QQ-C-390 | C-22229 Gr8 | |
| Aluminium bronze | 958 | QQ-C-390 | ||||
| Silicon bronze | 878 | B30 | 878 |
The following table outlines the chemical composition of various grades of copper alloys.