Silanes
In organosilicon chemistry, silanes are a diverse class of charge-neutral organic compounds with the general formula. The R substituents can be any combination of organic or inorganic groups. Most silanes contain Si-C bonds, and are discussed under organosilicon compounds. Some contain Si-H bonds and are discussed under hydrosilanes.
Examples
- Silane, the parent.
- Binary silicon-hydrogen compounds includes silane itself but also compounds with Si-Si bonds including disilane and longer chains.
- Silanes with one, two, three, or four Si-H bonds are called hydrosilanes. Silane is again the parent member. Examples: triethylsilane and triethoxysilane.
- Polysilanes are organosilicon compounds with the formula. They feature Si-Si bonds. Attracting more interest are the organic derivatives such as polydimethylsilane. Dodecamethylcyclohexasilane is an oligomer of such materials. Formally speaking, polysilanes also include compounds of the type, but these less studied.
- Carbosilanes are polymeric silanes with alternating Si-C bonds.
- Chlorosilanes have Si-Cl bonds. The dominant examples come from the Direct process, i.e., 4-xSiClx. Another important member is trichlorosilane.
- Organosilanes are a class of charge-neutral organosilicon compounds. Example: tetramethylsilane
Applications
Compound-specific applications are:- Polysilicone production
- PEX crosslinking agent
- Textile finishing industry
- Dentistry
- Integrated in battery materials to longevity
- Construction materials