TNT equivalent
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. A ton of TNT equivalent is a unit of energy defined by convention to be . It is the approximate energy released in the detonation of a metric ton of trinitrotoluene. In other words, for each gram of TNT exploded, of energy are released.
This convention intends to compare the destructiveness of an event with that of conventional explosive materials, of which TNT is a typical example, although other conventional explosives such as dynamite contain more energy.
A related concept is the physical quantity TNT-equivalent mass, expressed in the ordinary units of mass and its multiples: kilogram, megagram or tonne, etc.
Kiloton and megaton
The "kiloton " is a unit of energy equal to 4.184 terajoules. A kiloton of TNT can be visualized as a cube of TNT on a side.The "megaton " is a unit of energy equal to 4.184 petajoules.
The kiloton and megaton of TNT equivalent have traditionally been used to describe the energy output, and hence the destructive power, of a nuclear weapon. The TNT equivalent appears in various nuclear weapon control treaties, and has been used to characterize the energy released in asteroid impacts.
Historical derivation of the value
Alternative values for TNT equivalency can be calculated according to which property is being compared and when in the two detonation processes the values are measured.Where for example the comparison is by energy yield, an explosive's energy is normally expressed for chemical purposes as the thermodynamic work produced by its detonation. For TNT this has been accurately measured as 4,686 J/g from a large sample of air blast experiments, and theoretically calculated to be 4,853 J/g.
However, even on this basis, comparing the actual energy yields of a large nuclear device and an explosion of TNT can be slightly inaccurate. Small TNT explosions, especially in the open, do not tend to burn the carbon-particle and hydrocarbon products of the explosion. Gas-expansion and pressure-change effects tend to "freeze" the burn rapidly. A large, open explosion of TNT may maintain fireball temperatures high enough that some of those products do burn up with atmospheric oxygen.
Such differences can be substantial. For safety purposes, a range as wide as has been stated for a gram of TNT upon explosion. Thus one can state that a nuclear bomb has a yield of 15 kt, but the explosion of an actual pile of TNT may yield due to additional carbon/hydrocarbon oxidation not present with small open-air charges.
These complications have been sidestepped by convention. The energy released by one gram of TNT was arbitrarily defined as a matter of convention to be 4,184 J, which is exactly one kilocalorie.
| Grams TNT | Symbol | Tons TNT | Symbol | Energy | Corresponding mass loss |
| milligram of TNT | mg | nanoton of TNT | nt | 46.55 fg | |
| gram of TNT | g | microton of TNT | μt | 46.55 pg | |
| kilogram of TNT | kg | milliton of TNT | mt | 46.55 ng | |
| megagram of TNT | Mg | ton of TNT | t | 46.55 μg | |
| gigagram of TNT | Gg | kiloton of TNT | kt | 46.55 mg | |
| teragram of TNT | Tg | megaton of TNT | Mt | 46.55 g | |
| petagram of TNT | Pg | gigaton of TNT | Gt | ; | 46.55 kg |
Conversion to other units
1 ton of TNT equivalent is approximately:- calories
- joules
- British thermal units
- foot-pounds
- kilowatt-hours
- electronvolts
- kilograms mass equivalent
Examples
Relative effectiveness factor
The relative effectiveness factor relates an explosive's demolition power to that of TNT, in units of the TNT equivalent/kg. The RE factor is the relative mass of TNT to which an explosive is equivalent; the greater the RE, the more powerful the explosive.This enables engineers to determine the proper masses of different explosives when applying blasting formulas developed specifically for TNT. For example, if a timber-cutting formula calls for a charge of 1 kg of TNT, then based on octanitrocubane's RE factor of 2.38, it would take only 1.0/2.38 kg of it to do the same job. Using PETN, engineers would need 1.0/1.66 kg to obtain the same effects as 1 kg of TNT. With ANFO or ammonium nitrate, they would require 1.0/0.74 kg or 1.0/0.32 kg, respectively.
Calculating a single RE factor for an explosive is, however, impossible. It depends on the specific case or use. Given a pair of explosives where one can produce double the shockwave output, the difference in direct metal cutting ability may be quadruple for one type of metal and septuple for another type of metal. The relative differences between two explosives with shaped charges will be even greater. The table below should be taken as an example and not as a precise source of data.
| Explosive, grade | Density | Detonation vel. | Relative effectiveness |
| Ammonium nitrate | 0.88 | 2,700 | 0.32 |
| Mercury fulminate | 4.42 | 4,250 | 0.51 |
| Black powder | 1.65 | 400 | 0.55 |
| Hexamine dinitrate | 1.30 | 5,070 | 0.60 |
| Dinitrobenzene | 1.50 | 6,025 | 0.60 |
| HMTD | 0.88 | 4,520 | 0.74 |
| ANFO | 0.92 | 4,200 | 0.74 |
| Urea nitrate | 1.67 | 4,700 | 0.77 |
| TATP | 1.18 | 5,300 | 0.80 |
| Tovex Extra commercial product | 1.33 | 5,690 | 0.80 |
| Hydromite 600 commercial product | 1.24 | 5,550 | 0.80 |
| ANNMAL | 1.16 | 5,360 | 0.87 |
| Amatol | 1.50 | 6,290 | 0.91 |
| Nitroguanidine | 1.76 | 6,750 |
|
| Trinitrotoluene | 1.60 | 6,900 | 1.00 |
| Hexanitrostilbene | 1.70 | 7,080 | 1.05 |
| Nitrourea | 1.45 | 6,860 | 1.05 |
| Tritonal | 1.70 | 6,650 | 1.05 |
| Nickel hydrazine nitrate | 1.70 | 7,000 | 1.05 |
| Amatol | 1.55 | 6,570 | 1.10 |
| Nitrocellulose | 1.40 | 6,400 | 1.10 |
| Nitromethane | 1.13 | 6,360 | 1.10 |
| PBXW-126 | 1.80 | 6,450 | 1.10 |
| Diethylene glycol dinitrate | 1.38 | 6,610 | 1.17 |
| PBXIH-135 EB | 1.81 | 7,060 | 1.17 |
| PBXN-109 | 1.68 | 7,450 | 1.17 |
| Triaminotrinitrobenzene | 1.80 | 7,550 | 1.17 |
| Picric acid | 1.71 | 7,350 | 1.17 |
| Trinitrobenzene | 1.60 | 7,300 | 1.20 |
| Tetrytol | 1.60 | 7,370 | 1.20 |
| Dynamite, Nobel's | 1.48 | 7,200 | 1.25 |
| Tetryl | 1.71 | 7,770 | 1.25 |
| Torpex | 1.80 | 7,440 | 1.30 |
| Composition B | 1.72 | 7,840 | 1.33 |
| Composition C-3 | 1.60 | 7,630 | 1.33 |
| Composition C-4 | 1.59 | 8,040 | 1.34 |
| Pentolite | 1.66 | 7,520 | 1.33 |
| Semtex 1A | 1.55 | 7,670 | 1.35 |
| Hexal | 1.79 | 7,640 | 1.35 |
| RISAL P | 1.39 | 5,980 | 1.40 |
| Hydrazine nitrate | 1.59 | 8,500 | 1.42 |
| Mixture: 24% nitrobenzene + 76% TNM | 1.48 | 8,060 | 1.50 |
| Mixture: 30% nitrobenzene + 70% nitrogen tetroxide | 1.39 | 8,290 | 1.50 |
| Nitroglycerin | 1.59 | 7,700 | 1.54 |
| Methyl nitrate | 1.21 | 7,900 | 1.54 |
| Octol | 1.83 | 8,690 | 1.54 |
| Nitrotriazolone | 1.87 | 8,120 | 1.60 |
| DADNE | 1.77 | 8,330 | 1.60 |
| Gelignite | 1.60 | 7,970 | 1.60 |
| Plastics Gel | 1.51 | 7,940 | 1.60 |
| Composition A-5 | 1.65 | 8,470 | 1.60 |
| Erythritol tetranitrate | 1.72 | 8,206 | 1.60 |
| Hexogen | 1.78 | 8,600 | 1.60 |
| PBXW-11 | 1.81 | 8,720 | 1.60 |
| Penthrite | 1.77 | 8,400 | 1.66 |
| Ethylene glycol dinitrate | 1.49 | 8,300 | 1.66 |
| MEDINA | 1.65 | 8,700 | 1.70 |
| Trinitroazetidine | 1.86 | 9,597 | 1.70 |
| Octogen | 1.95 | 9,100 | 1.70 |
| Hexanitrobenzene | 1.97 | 9,340 | 1.80 |
| Hexanitrohexaazaisowurtzitane | 1.97 | 9,500 | 1.90 |
| AFX-757 | 1.84 | 6,080 | 1.90 |
| DDF | 1.98 | 10,000 | 1.95 |
| Heptanitrocubane | 1.92 | 9,200 | N/A |
| Octanitrocubane | 1.95 | 10,600 | 2.38 |
| Octaazacubane | 2.69 | 15,000 |