Frozen food
food preserves it from the time it is prepared to the time it is eaten. Since early times, farmers, fishermen, and trappers have preserved grains and produce in unheated buildings during the winter season. Freezing food slows decomposition by turning residual moisture into ice, inhibiting the growth of most bacterial species. In the food commodity industry, there are two processes: mechanical and cryogenic. The freezing kinetics is important to preserve the food quality and texture. Quicker freezing generates smaller ice crystals and maintains cellular structure. Cryogenic freezing is the quickest freezing technology available due to the ultra low liquid nitrogen temperature.
Preserving food in domestic kitchens during modern times is achieved using household freezers. Accepted advice to householders was to freeze food on the day of purchase. An initiative by a supermarket group in 2012 promotes the freezing of food "as soon as possible up to the product's 'use by' date". The Food Standards Agency was reported as supporting the change, provided the food had been stored correctly up to that time.
Preservatives
Frozen products do not require any added preservatives because microorganisms do not grow when the temperature of the food is below, which is sufficient on its own in preventing food spoilage. Long-term preservation of food may call for food storage at even lower temperatures. Carboxymethylcellulose, a tasteless and odorless stabilizer, is typically added to frozen food because it does not adulterate the quality of the product.History
Natural food freezing had been in use by people in cold climates for centuries.In 1861 Thomas Sutcliffe Mort established at Darling Harbour in Sydney, Australia, the world's first freezing works, which later became the New South Wales Fresh Food and Ice Company. Mort financed experiments by Eugene Dominic Nicolle, a French born engineer who had arrived in Sydney in 1853 and registered his first ice-making patent in 1861. The first trial shipment of frozen meat to London was in 1868. Although their machinery was never used in the frozen meat trade, Mort and Nicolle developed commercially viable systems for domestic trade. The financial return on that investment was minimal for Mort. Regular shipments of frozen meat from Australia and New Zealand to Europe began in 1881, with a consignment of frozen New Zealand sheep exported to London on board the Dunedin.
By 1885 a small number of chickens and geese were being shipped from Russia to London in insulated cases using this technique. By March 1899, the "British Refrigeration and Allied Interests" reported that a food importing business, "Baerselman Bros", was shipping some 200,000 frozen geese and chickens per week from three Russian depots to New Star Wharf, Lower Shadwell, London over three or four winter months. This trade in frozen food was enabled by the introduction of Linde cold air freezing plants in three Russian depots and the London warehouse. The Shadwell warehouse stored the frozen goods until they were shipped to markets in London, Birmingham, Liverpool and Manchester. The techniques were later expanded to the meat-packing industry.
From 1929, Clarence Birdseye introduced "flash freezing" to the American public. Birdseye first became interested in food freezing during fur-trapping expeditions to Labrador in 1912 and 1916, where he saw the natives use natural freezing to preserve foods. A 1920s hunting trip to Canada, where he witnessed the traditional methods of the indigenous Inuit, directly inspired Birdseye's food preserving method.
The Icelandic Fisheries Commission was created in 1934 to initiate innovation in the industry, and encouraged fishermen to start quick-freezing their catch.
Íshúsfélag Ísfirðinga, one of the first frozen fish companies, was formed in Ísafjörður, Iceland, by a merger in 1937.
More advanced attempts include food frozen for Eleanor Roosevelt on her trip to Russia. Other experiments involving orange juice, ice cream and vegetables were conducted by the military near the end of World War II.
Technology
The freezing technique itself, just like the frozen food market, is developing to become faster, more efficient and more cost-effective. As demonstrated by Birdseye's work, faster freezing means smaller ice crystals and a better-preserved product.Birdseye's original cryogenic freezing approach using immersion in liquid nitrogen is still used. Due to its cost, however, use is limited to fish fillets, seafood, fruits, and berries. It is also possible to freeze food by immersion in the warmer, but cheaper, liquid carbon dioxide, which can be produced by mechanical freezing.
Most frozen food is instead frozen using a mechanical process using the vapor-compression refrigeration technology similar to ordinary freezers. Such a process is cheaper at scale, but is usually slower. Nevertheless, a wide variety of processes have been devised to achieve faster heat transfer from the food to the refrigerant:
- Air-blast freezing is the oldest and cheapest approach. Food is placed into freezing rooms where the air is cold. Air is either forced onto the food or left static. This setup allows large chunks of food to be more easily processed compared to other methods, but is quite slow.
- * Belt freezers simply put a conveyor belt inside a cold room.
- * Tunnel freezing is a variant of air-blast freezing where food is put onto trolley racks and sent into a tunnel where cold air is continuously circulated.
- * Fluidized bed freezing is a variant of air-blast freezing where pelletized food is blown by fast-moving cold air from below, forming a fluidized bed. The small size of the food combined with the fast-flowing air provides good heat transfer and therefore quicker freezing.
- Contact freezing uses physical contact other than air to transfer the heat. Direct contact freezing puts the product directly in contact with the refrigerant, while indirect contact freezing uses a plate in between.
- * Plate freezing is the most common form of contact freezing. Food is put between cold metal plates and then lightly pressed to maintain contact.
- * Contact belt freezing combines a conveyor belt with plate freezing. It is usually used for fruit pulps, egg yolk, sauces and soups.
- * Immersion freezing dips the product into a cold refrigerant liquid to freeze it, usually on a conveyor belt. The product may be in direct contact with the liquid, or be separated by a membrane. It can be used for freezing the outer shell of large particles to reduce water loss.
Packaging
Frozen food packaging must maintain its integrity throughout filling, sealing, freezing, storage, transportation, thawing, and often cooking. As many frozen foods are cooked in a microwave oven, manufacturers have developed packaging that can go directly from freezer to the microwave.In 1974, the first differential heating container was sold to the public. A DHC is a sleeve of metal designed to allow frozen foods to receive the correct amount of heat. Various sized apertures were positioned around the sleeve. The consumer would put the frozen dinner into the sleeve according to what needed the most heat. This ensured proper cooking.
Today there are multiple options for packaging frozen foods. Boxes, cartons, bags, pouches, boil-in-bags, lidded trays and pans, crystallized PET trays, and composite and plastic cans.
Scientists continue to research new aspects of frozen food packaging. Active packaging offers many new technologies that can actively sense and then neutralize the presence of bacteria or other harmful species. Active packaging can extend shelf-life, maintain product safety, and help preserve the food over a longer period of time. Several functions of active packaging are being researched:
- Oxygen scavengers
- Time temperature indicators and digital temperature data loggers
- Antimicrobials
- Carbon dioxide controllers
- Microwave susceptors
- Moisture control: water activity, moisture vapor transmission rate, etc.
- Flavor enhancers
- Odor generators
- Oxygen-permeable films
- Oxygen generators
Effects on nutrients
Vitamin content of frozen fruits and vegetables
- Vitamin C: Usually lost in a higher concentration than any other vitamin. A study was performed on peas to determine the cause of vitamin C loss. A vitamin loss of 10% occurred during the blanching phase with the rest of the loss occurring during the cooling and washing stages. The vitamin loss was not actually accredited to the freezing process. Another experiment was performed involving peas and lima beans. Frozen and canned vegetables were both used in the experiment. The frozen vegetables were stored at and the canned vegetables were stored at room temperature. After 0, 3, 6, and 12 months of storage, the vegetables were analyzed with and without cooking. O'Hara, the scientist performing the experiment said, "From the view point of the vitamin content of the two vegetables when they were ready for the plate of the consumer, there did not appear to be any marked advantages attributable to method of preservation, frozen storage, processed in a tin, or processed in glass."
- Vitamin B1 : A vitamin loss of 25% is normal. Thiamin is easily soluble in water and is destroyed by heat.
- Vitamin B2 : Not much research has been done to determine how freezing affects riboflavin levels. Studies that have been performed are inconclusive. One study found an 18% vitamin loss in green vegetables, while another found a 4% loss. It is commonly accepted that the loss of riboflavin has to do with the preparation for freezing rather than the freezing process itself.
- Vitamin A : There is little loss of carotene during preparation for freezing and freezing of most vegetables. Much of the vitamin loss is incurred during the extended storage period.