Faraday efficiency

In electrochemistry, Faraday efficiency describes the efficiency with which charge is transferred in a system facilitating an electrochemical reaction. The word "Faraday" in this term has two interrelated aspects: first, the historic unit for charge is the faraday, but has since been replaced by the coulomb ; and secondly, the related Faraday's constant correlates charge with moles of matter and electrons. This phenomenon was originally understood through Michael Faraday's work and expressed in his laws of electrolysis.

Methods of measuring faradaic loss

Faradaic efficiency of a cell design is usually measured through bulk electrolysis where a known quantity of reagent is stoichiometrically converted to product, as measured by the current passed. This result is then compared to the observed quantity of product measured through another analytical method.

Faradaic loss vs. voltage and energy efficiency

Faradaic loss is only one form of energy loss in an electrochemical system. Another is overpotential, the difference between the theoretical and actual electrode voltages needed to drive the reaction at the desired rate. Even a rechargeable battery with 100% faradaic efficiency requires charging at a higher voltage than it produces during discharge, so its overall energy efficiency is the product of voltage efficiency and faradaic efficiency. Voltage efficiencies below 100% reflect the thermodynamic irreversibility of every real-world chemical reaction.