Dimethyl sulfite


Dimethyl sulfite is a sulfite ester with the chemical formula 2SO.
Dimethyl sulfite is used as an additive in some polymers to prevent oxidation. It is also a potentially useful high energy battery electrolyte solvent.

Structure and conformation

The dimethyl sulfite molecule can adopt several conformations. The most stable is the GG conformer. Each C–O bond is gauche to the S=O bond, depicted below.

Preparation

Dimethyl sulfite is prepared from a 1:2 ratio of thionyl chloride and methanol. The reaction can be catalyzed by tertiary amine bases and likely proceeds via the chlorosulfinate, this intermediate will exist only fleetingly in the presence of methanol and as such its decomposition to methyl chloride and sulfur dioxide is not observed to any great extent.