Transient equilibrium


In nuclear physics, transient equilibrium is a situation in which equilibrium is reached by a parent-daughter radioactive isotope pair where the half-life of the daughter is shorter than the half-life of the parent. Contrary to secular equilibrium, the half-life of the daughter is not negligible compared to parent's half-life. An example of this is a molybdenum-99 generator producing technetium-99 for nuclear medicine diagnostic procedures. Such a generator is sometimes called a cow because the daughter product, in this case technetium-99, is milked at regular intervals. Transient equilibrium occurs after four half-lives, on average.

Activity in transient equilibrium

The activity of the daughter is given by the Bateman equation:
where and are the activity of the parent and daughter, respectively. and are the half-lives of the parent and daughter, respectively, and BR is the branching ratio.
In transient equilibrium, the Bateman equation cannot be simplified by assuming the daughter's half-life is negligible compared to the parent's half-life. The ratio of daughter-to-parent activity is given by:

Time of maximum daughter activity

In transient equilibrium, the daughter activity increases and eventually reaches a maximum value that can exceed the parent activity. The time of maximum activity is given by:
where and are the half-lives of the parent and daughter, respectively. In the case of ^Tc-^Mo generator, the time of maximum activity is approximately 24 hours, which makes it convenient for medical use.