Frost
Frost is a layer of ice on a solid surface, which forms from water vapor that deposits onto a freezing surface. Frost forms when the air contains more water vapor than it can normally hold at a specific temperature. The process is similar to the formation of dew, except it occurs below the freezing point of water typically without crossing through a liquid state.
Air always contains a certain amount of water vapor, depending on temperature. Warmer air can hold more than colder air. When the atmosphere contains more water than it can hold at a specific temperature, its relative humidity rises above 100% becoming supersaturated, and the excess water vapor is forced to deposit onto any nearby surface, forming seed crystals. The temperature at which it will form is called the dew point, and depends on the humidity of air. When the temperature of the air drops below its dew point, excess water vapor is forced out of solution, resulting in a phase change directly from water vapor to ice. As more water molecules are added to the seeds, crystal growth occurs, forming ice crystals. Crystals may vary in size and shape, from an even layer of numerous microscopic-seeds to fewer but much larger crystals, ranging from long dendritic crystals growing across a surface, acicular crystals growing outward from the surface, snowflake-shaped crystals, or even large, knifelike blades of ice covering an object, which depends on many factors such as temperature, air pressure, air motion and turbulence, surface roughness and wettability, and the level of supersaturation. For example, water vapor adsorbs to glass very well, so automobile windows will often frost before the paint, and large hoar-frost crystals can grow very rapidly when the air is very cold, calm, and heavily saturated, such as during an ice fog.
Frost may occur when warm, moist air comes into contact with a cold surface, cooling it below its dew point, such as warm breath on a freezing window. In the atmosphere, it more often occurs when both the air and the surface are below freezing, when the air experiences a drop in temperature bringing it below its dew point, for example, when the temperature falls after the sun sets. In temperate climates, it most commonly appears on surfaces near the ground as fragile white crystals; in cold climates, it occurs in a greater variety of forms. The propagation of crystal formation occurs by the process of nucleation, in specific, water nucleation, which is the same phenomenon responsible for the formation of clouds, fog, snow, rain and other meteorological phenomena.
The ice crystals of frost form as the result of fractal process development. The depth of frost crystals varies depending on the amount of time they have been accumulating, and the concentration of the water vapor. Frost crystals may be invisible, clear, or, if a mass of frost crystals scatters light in all directions, the coating of frost appears white.
Types of frost include crystalline from deposition of water vapor from air of low humidity, white frost in humid conditions, window frost on glass surfaces, advection frost from cold wind over cold surfaces, black frost without visible ice at low temperatures and very low humidity, and [|rime] under supercooled wet conditions.
Plants that have evolved in warmer climates suffer damage when the temperature falls low enough to freeze the water in the cells that make up the plant tissue. The tissue damage resulting from this process is known as "frost damage". Farmers in those regions where frost damage has been known to affect their crops often invest in substantial means to protect their crops from such damage.
Formation
If a solid surface is chilled below the dew point of the surrounding humid air, and the surface itself is colder than freezing, ice will form on it. If the water deposits as a liquid that then freezes, it forms a coating that may look glassy, opaque, or crystalline, depending on its type. Depending on context, that process may also be called atmospheric icing. The ice it produces differs in some ways from crystalline frost, which consists of spicules of ice that typically project from the solid surface on which they grow.The main difference between the ice coatings and frost spicules arises because the crystalline spicules grow directly from desublimation of water vapour from air, and desublimation is not a factor in icing of freezing surfaces. For desublimation to proceed, the surface must be below the frost point of the air, meaning that it is sufficiently cold for ice to form without passing through the liquid phase. The air must be humid, but not sufficiently humid to permit the condensation of liquid water, or icing will result instead of desublimation. The size of the crystals depends largely on the temperature, the amount of water vapor available, and how long they have been growing undisturbed.
As a rule, except in conditions where supercooled droplets are present in the air, frost will form only if the deposition surface is colder than the surrounding air. For instance, frost may be observed around cracks in cold wooden sidewalks when humid air escapes from the warmer ground beneath. Other objects on which frost commonly forms are those with low specific heat or high thermal emissivity, such as blackened metals, hence the accumulation of frost on the heads of rusty nails.
The apparently erratic occurrence of frost in adjacent localities is due partly to differences of elevation, the lower areas becoming colder on calm nights. Where static air settles above an area of ground in the absence of wind, the absorptivity and specific heat of the ground strongly influence the temperature that the trapped air attains.
Types
Hoar frost
Hoar frost, also hoarfrost, radiation frost, or pruina, refers to white ice crystals deposited on the ground or loosely attached to exposed objects, such as wires or leaves. They form on cold, clear nights when conditions are such that heat radiates into outer space faster than it can be replaced from nearby warm objects or brought in by the wind. Under suitable circumstances, objects cool to below the frost point of the surrounding air, well below the freezing point of water. Such freezing may be promoted by effects such as flood frost or frost pocket. These occur when ground-level radiation cools air until it flows downhill and accumulates in pockets of very cold air in valleys and hollows. Hoar frost may freeze in such low-lying cold air even when the air temperature a few feet above ground is well above freezing.The word "hoar" comes from an Old English adjective that means "showing signs of old age". In this context, it refers to the frost that makes trees and bushes look like white hair.
Hoar frost may have different names depending on where it forms:
- Air hoar is a deposit of hoar frost on objects above the surface, such as tree branches, plant stems, and wires.
- Surface hoar refers to fern-like ice crystals directly deposited on snow, ice, or already frozen surfaces.
- Crevasse hoar consists of crystals that form in glacial crevasses where water vapour can accumulate under calm weather conditions.
- Depth hoar refers to faceted crystals that have slowly grown large within cavities beneath the surface of banks of dry snow. Depth hoar crystals grow continuously at the expense of neighbouring smaller crystals, so typically are visibly stepped and have faceted hollows.
In very low temperatures where fluffy surface hoar crystals form without subsequently being covered with snow, strong winds may break them off, forming a dust of ice particles and blowing them over the surface. The ice dust then may form yukimarimo, as has been observed in parts of Antarctica, in a process similar to the formation of dust bunnies and similar structures.
Hoar frost and white frost also occur in man-made environments such as in freezers or industrial cold-storage facilities. If such cold spaces or the pipes serving them are not well insulated and are exposed to ambient humidity, the moisture will freeze instantly depending on the freezer temperature. The frost may coat pipes thickly, partly insulating them, but such inefficient insulation still is a source of heat loss.
Advection frost
Advection frost refers to tiny ice spikes that form when very cold wind is blowing over tree branches, poles, and other surfaces. It looks like rimming on the edges of flowers and leaves, and usually forms against the direction of the wind. It can occur at any hour, day or night.Window frost
Window frost forms when a glass pane is exposed to very cold air on the outside and warmer, moderately moist air on the inside. If the pane is a bad insulator, water vapour condenses on the glass, forming frost patterns. With very low temperatures outside, frost can appear on the bottom of the window even with double-pane energy-efficient windows because the air convection between two panes of glass ensures that the bottom part of the glazing unit is colder than the top part. On unheated motor vehicles, the frost usually forms on the outside surface of the glass first. The glass surface influences the shape of crystals, so imperfections, scratches, or dust can modify the way ice nucleates. The patterns in window frost form a fractal with a fractal dimension greater than one, but less than two. This is a consequence of the nucleation process being constrained to unfold in two dimensions, unlike a snowflake, which is shaped by a similar process, but forms in three dimensions and has a fractal dimension greater than two.If the indoor air is very humid, rather than moderately so, water first condenses in small droplets, and then freezes into clear ice.
Similar patterns of freezing may occur on other smooth vertical surfaces, but they seldom are as obvious or spectacular as on clear glass.