Lanthanum phosphide

Lanthanum phosphide is an inorganic compound of lanthanum and phosphorus with the chemical formula LaP.

Synthesis

Lanthanum phosphide can be made by heating lanthanum metal with excess phosphorus in a vacuum:

Physical properties

Lanthanum phosphide forms black crystals of a cubic system, space group Fmm, cell parameters a = 0.6025 nm, with number of formulas per unit cell Z = 4.
The crystals are very unstable and decompose in the open air.

Electronic properties

Lanthanum phosphide is an example of a strongly correlated material, complicating theoretical prediction of its properties.
According to HSE06 calculations, lanthanum phosphide has been theoretically predicted to have an indirect band gap of 0.25 eV along the Γ-X direction. According to HSE06 calculations with spin-orbit coupling, the band gap is predicted to be a direct gap of 0.72 eV at the X point. Using EVGGA, the compound is predicted to have a band gap of 0.56 eV along the Γ-X direction. FP-LAPW has predicted an indirect gap of 0.33 eV along the Γ-X direction.

Chemical properties

Lanthanum phosphide reacts with water, releasing highly toxic phosphine gas:

Uses

Lanthanum phosphide compound is a semiconductor used in high power, high frequency applications, and in laser diodes.

Lanthanum polyphosphide

In addition to the simple phosphide, LaP, lanthanum and phosphorus can also form phosphorus-rich compounds such as LaP₂ LaP₅ and LaP₇.